Diene polymer and process for producing the same

ABSTRACT

A polymer containing units represented by the defined formula (1); and a process for producing the polymer, which comprises the step of polymerizing a compound represented by the defined formula (3), the units represented by the formula (1) being polymerized units of the compound represented by the formula (3) such as 1,6-heptadiene.

FIELD OF THE INVENTION

The present invention relates to a diene polymer having a superiorbalance between a heat resistance and workability, and a process forproducing the diene polymer.

BACKGROUND OF THE INVENTION

There cannot be obtained diene polymers having a superior balancebetween a heat resistance and workability, by means of polymerizingnon-conjugated diene compounds such as 1,6-heptadiene represented by thehereinafter-mentioned formula (3) having two carbon-to-carbon doublebonds, in the presence of a commonly-used addition polymerizationcatalyst. The reason is that one of the two carbon-to-carbon doublebonds is involved in not an addition polymerization reaction but anundesirable reaction such as a cross-linking reaction, although anothercarbon-to-carbon double bond is involved in an addition polymerizationreaction, and as a result, there is obtained only a polymer, which (i)has no cyclic structure in its main chain contributing to a heatresistance, and (ii) is not necessarily a thermoplastic polymercontributing to workability.

On the other hand, an ethylene-cyclopentane alternating copolymer, whichis obtained by coordination ring-opening polymerization, and isdisclosed in Macromolecules, Vol. 35, pages 9640-9647 (2002), has aproblem in that (i) the copolymer needs to be molded at a hightemperature of 200° C. or higher, because of its high meting point of180° C. or higher, and (ii) a polymer product of coordinationring-opening polymerization needs to be further hydrogenated, in orderto obtain the ethylene-cyclopentane alternating copolymer, although thecopolymer has a cyclic structure in its main chain contributing to aheat resistance.

SUMMARY OF THE INVENTION

In view of the above-mentioned circumstances, the present invention hasan object to provide a diene polymer having a superior balance between aheat resistance and workability, and a process for producing the dienepolymer.

The present invention is a polymer containing units represented by thefollowing formula (1):

wherein A¹, A², A³, A⁴, A⁵, A⁶, A⁷, A⁸, A⁹, A¹⁰, A¹¹, and A¹² areindependently of one another a hydrogen atom, a halogen atom, a hydroxylgroup, a nitrile group, an alkyl group, an aralkyl group, a silyl group,a siloxy group, an amino group, an amide group, an imide group, or ahydrocarbylthio group, and A³ and A⁴, A⁵ and A⁶, or A¹¹ and A¹² may belinked with each other to form a ring; m is 0 or 1; and n is an integerof 1 to 20.

Also, the present invention is a process for producing a polymercontaining units represented by the above formula (1), which comprisesthe step of polymerizing a compound represented by the following formula(3):

wherein Z is a group of —(CH₂)_(n-1)—(CA⁹A¹⁰)_(m)H; two wavy linesdisplayed in the upper right of the formula (3) mean variety in theirconfiguration; and A¹ to A¹², m and n are the same as those defined inthe formula (1).

In the present invention, the term “unit” contained in theabove-mentioned “units represented by the formula (1)” means apolymerization unit of a monomer such as a compound represented by theformula (3).

DETAILED DESCRIPTION OF THE INVENTION

Examples of the halogen atom of A¹ to A¹² in the above formulas are afluorine atom, a chlorine atom, a bromine atom, and an iodine atom.Among them, preferred is a fluorine atom.

Examples of the alkyl group of A¹ to A¹² in the above formulas arelinear alkyl groups such as a methyl group, an ethyl group, and an-butyl group; branched alkyl groups such as an isopropyl group, anisobutyl group, a tert-butyl group, and a neopentyl group; and cyclicalkyl groups such as a cyclohexyl group and a cyclooctyl group.

Examples of the aralkyl group of A¹ to A¹² in the above formulas are abenzyl group, a phenethyl group, a 2-methylbenzyl group, a3-methylbenzyl group, a 4-methylbenzyl group, a 2,6-dimethylbenzylgroup, and a 3,5-dimethylbenzyl group. The aralkyl group may have asubstituent such as a halogen atom, a hydrocarbyloxy group, a nitrogroup, a sulfonate group, a silyl group, and a cyano group.

Examples of the silyl group of A¹ to A¹² in the above formulas aremono-substituted silyl groups such as a methylsilyl group, an ethylsilylgroup, and a phenylsilyl group; di-substituted silyl groups such as adimethylsilyl group, a diethylsilyl group, and a diphenylsilyl group;and tri-substituted silyl groups such as a trimethylsilyl group, atrimethoxysilyl group, a dimethylmethoxysilyl group, amethyldimethoxysilyl group, a triethylsilyl group, a triethoxysilylgroup, a tri-n-propylsilyl group, a triisopropylsilyl group, atri-n-butylsilyl group, a tri-sec-butylsilyl group, atert-butyldimethylsilyl group, a triisobutylsilyl group, atert-butyldiphenylsilyl group, a cyclohexyldimethylsilyl group, atricyclohexylsilyl group, and a triphenylsilyl group. The silyl groupmay have a substituent such as a halogen atom, a hydrocarbyloxy group, anitro group, a sulfonate group, a silyl group, and a cyano group.

Examples of the siloxy group of A¹ to A¹² in the above formulas are atrimethylsiloxy group, a triisopropylsiloxy group, a diethylmethylsiloxygroup, an ethyldimethylsiloxy group, a triethoxysiloxy group, atri-n-propylsiloxy group, a triisopropylsiloxy group, atri-n-butylsiloxy group, a tri-sec-butylsiloxy group, atert-butyldimethylsiloxy group, a tert-butyldiphenylsiloxy group, acyclohexyldimethylsiloxy group, a cyclohexyldiphenylsiloxy group, atricyclohexylsiloxy group, and a triethoxysiloxy group. The siloxy groupmay have a substituent such as a halogen atom, a hydrocarbyloxy group, anitro group, a sulfonate group, a silyl group, and a cyano group.

Examples of the amino group of A¹ to A¹² in the above formulas arelinear alkylamino groups such as an N-methylamino group, an N-ethylaminogroup, an N-n-butylamino group, an N,N-dimethylamino group, anN,N-diethylamino group, and an N,N-di-n-butylamino group; branchedalkylamino groups such as an N,N-diisopropylamino group, anN,N-diisobutylamino group, an N,N-di-tert-butylamino group, and anN,N-dineopentylamino group; and cyclic alkylamino groups such as anN,N-dicyclohexylamino group and an N,N-dicyclooctylamino group.

Examples of the amide group of A¹ to A¹² in the above formulas are anethanamide group, an N-n-butylethanamide group, an N-methylethanamidegroup, an N-ethylethanamide group, an N-n-butylhexanamide group, anisopropanamide group, an isobutanamide group, a tert-butanamide group, aneopentanamide group, a cyclohexanamide group, and a cyclooctanamidegroup.

Examples of the imide group of A¹ to A¹² in the above formulas are asuccinimide group, a maleimide group, and a phthalimide group.

Examples of the hydrocarbylthio group of A¹ to A¹² in the above formulasare linear alkylthio groups such as a methylthio group, an ethylthiogroup, and a n-butylthio group; branched alkylthio groups such as anisopropylthio group, an isobutylthio group, a tert-butylthio group, anda neopentylthio group; and cyclic alkylthio groups such as acyclohexylthio group and a cyclooctylthio group.

Among them, A¹ to A¹² are preferably a hydrogen atom, a halogen atom, oran alkyl group having 1 to 10 carbon atoms; more preferably a hydrogenatom or a methyl group; and further preferably a hydrogen atom.

Each of A³ and A⁴, A⁵ and A⁶, or A¹¹ and A¹² may be linked with eachother to form a ring. Examples of the ring are aliphatic rings such as acyclobutane ring, a cyclopentane ring and a cyclohexane ring. Thoserings may have one or more substituents.

A relative configuration between A⁷ and A⁸ in the formula (1) is notparticularly limited. The configuration is preferably a trans-formrepresented by the following formula (2), in order to improve a heatresistance of the diene polymer of the present invention; and from aviewpoint of an excellent heat resistance of the diene polymer, the unitrepresented by the formula (2) is contained in the diene polymer in anamount of preferably 50% by mol or larger, and more preferably 95% bymol or larger, the total amount of the unit represented by the formula(1) being 100% by mol:

wherein all the symbols contained in the formula (2) are the same asthose defined in the formula (1).

A proportion of the above-mentioned trans-form is measured with a¹³C-NMR spectrum, which is obtained using a chloroform-d₁ solution ofthe polymer of the present invention. A peak (i) appearing at 45 to 48ppm in the ¹³C-NMR spectrum is assigned to carbon atoms having atrans-form configuration, and a peak (ii) appearing at 39 to 42 ppmtherein is assigned to carbon atoms having a cis-form configuration,provided that a peak assigned to chloroform-d₁ appears at 77 ppm.Therefore, the proportion (% by mol) of the trans-form is obtained fromthe following formula:proportion (% by mol) of trans-form =area of peak (i)×100/[area of peak(i)+area of peak (ii)].

Stereoregularity of the polymer of the present invention is determinedby an absolute configuration of the two asymmetric carbon atoms, whichare linked to A⁷ and A⁸, respectively, and exist in the main chain ofthe polymer having the unit represented by the formula (1). There arefour kinds of polymers in view of said stereoregularity, (a) anerythrodiisotactic polymer, (b) an erythrodisyndiotactic polymer, (c) athreodiisotactic polymer, and (d) a threodisyndiotactic polymer, asshown in the following formulas:

wherein C¹ means a carbon atom linked to A³ and A⁴ in the formula (1);C² means a carbon atom linked to A⁵ and A⁶ therein; a curved linebetween C¹ and C² corresponds to the tree bonds existing between thecarbon atom linked to A³ and A⁴ and the carbon atom linked to A⁵ and A⁶;and other carbon atoms and other substituents contained in the unitrepresented by the formula (1) are abbreviated.

The above-mentioned four kinds of polymers are defined in Encyclopediaof Polymer Science and Engineering (USA), 2nd Ed., Vol. 10, pages191-203, John Wiley & Sons, 1987.

Stereoregularity of the polymer of the present invention is notparticularly limited. From a viewpoint of production of a polymerexcellent in its heat resistance, the polymer of the present inventionis (i) a polymer having an erythrodiisotactic triad or athreodiisotactic triad in an amount of preferably more than 25% by mol,more preferably 30% by mol or more, and further preferably 50% by mol ormore, the total amount of the unit represented by the formula (1) being100% by mol, or (ii) a polymer having an erythrodisyndiotactic triad ora threodisyndiotactic triad in an amount of preferably more than 25% bymol, more preferably 30% by mol or more, and further preferably 50% bymol or more, the total amount of the unit represented by the formula (1)being 100% by mol.

The above-mentioned stereoregularity is determined with a ¹³C-NMRspectrum obtained by use of a solution of the polymer of the presentinvention in chloroform-d₁. A peak (iii) appearing at 46.2 to 46.6 ppmin the ¹³C-NMR spectrum is assigned to carbon atoms derived from athreodiisotactic triad, and a peak (iv) appearing at 46.9 to 47.3 ppmtherein is assigned to carbon atoms derived from a threodisyndiotactictriad, provided that a peak assigned to chloroform-d₁ appears at 77 ppm.

Therefore, a proportion (%) of the above-mentioned threodiisotactictriad is derived form the following formula:Proportion (%) of threodiisotactic triad=area of peak (iii)×100/[area ofpeak (iii)+area of peak (iv)];anda proportion (%) of the above-mentioned threodisyndiotactic triad isderived form the following formula:Proportion (%) of threodisyndiotactic triad=area of peak (iv)×100/[areaof peak (iii)+area of peak (iv)].

Z in the formula (3) is preferably a hydrogen atom (m=0 and n=1), or analkyl group having 1 to 20 carbon atoms (m=1, n=1 to 20, A⁹=H, andA¹⁰=H).

Compounds represented by the formula (3) may be known in the art.Particularly preferable examples thereof are alkyldienes such as1,6-heptadiene, 1,6-octadiene, 1,6-nanodiene, 1,6-decadiene, and1,6-undecadiene; 4-alkyloxy-1,6-heptadienes such as4-methoxy-1,6-heptadiene, 4-ethoxy-1,6-heptadiene,4-(n-isopropoxy)-1,6-heptadiene, 4-isopropoxy-1,6-heptadiene,4-(n-butoxy)-1,6-heptadiene, 4-sec-butoxy-1,6-heptadiene,4-tert-butoxy-1,6-heptadiene, 4-neopentoxy-1,6-heptadiene,4-(2′-norborneoxy)-1,6-heptadiene, and 4-adamantoxy-1,6-heptadiene;4-aralkyloxy-1,6-heptadienes such as 4-(benzyloxy)-1,6-heptadiene,4-(homobenzyloxy)-1,6-heptadiene,4-(2′-naphthylmethyloxy)-1,6-heptadiene,4-(9′-fluorenylmethyloxy)-1,6-heptadiene, and4-(benzyloxymethoxy)-1,6-heptadiene; 4-aryloxy-1,6-heptadienes such as4-phenoxy-1,6-heptadiene, 4-(2′-naphthyloxy)-1,6-heptadiene, and4-(9′-fluorenyloxy)-1,6-heptadiene; and 4-(tri-substitutedsiloxy)-1,6-heptadienes such as 4-(trimethylsiloxy)-1,6-heptadiene,4-(triethylsiloxy)-1,6-heptadiene, 4-(triphenylsiloxy)-1,6-heptadiene,4-(triisopropylsiloxy)-1,6-heptadiene,4-(tert-butyldimethylsiloxy)-1,6-heptadiene,4-(dimethylcyclohexylsiloxy)-1,6-heptadiene, and4-(diphenyl-tert-butylsiloxy)-1,6-heptadiene.

Examples of the polymer of the present invention are homopolymersobtained by homopolymerizing each of the above-mentioned compounds.Representative examples of the homopolymer are poly-1,6-heptadiene,poly-4-(triisopropylsiloxy)-1,6-heptadiene, andpoly-4-(tert-butyldimethylsiloxy)-1,6-heptadiene.

The polymer of the present invention can be prepared by polymerizing thecompound represented by the formula (3). The polymerization ispreferably carried out in the presence of a polymerization catalystformed by contacting a transition metal compound with an organoaluminumcompound and/or boron compound.

The transition metal compound is not particularly limited as long as ithas an addition polymerization activity, and may be a compound known inthe art. Among them, preferred is a transition metal compound having atransition metal of Groups 4 to 10 or lanthanide series in the PeriodicTable of the elements. Examples of the transition metal compound arethose represented by the following formula (4), and a μ-oxo transitionmetal compound, which is a dimmer obtained by reacting the transitionmetal compound with water:L_(a)M¹X¹ _(b)  (4)wherein M¹ is a transition metal atom of Groups 4 to 10 or lanthanideseries of the Periodic Table of the elements (IUPAC 1985); L is acyclopentadiene-containing anionic group or a hetero atom-having group,and when plural Ls exist, they may be linked with one another directlyor through a group having a carbon atom, a silicon atom, a nitrogenatom, an oxygen atom, a sulfur atom or a phosphor atom; X¹ is a halogenatom or a hydrocarbyl group having 1 to 20 carbon atoms; a is a numbersatisfying 0<a≦8; and b is a number satisfying 0<a≦8.

Examples of M¹ are a titanium atom, a zirconium atom, a hafnium atom, avanadium atom, a niobium atom, a tantalum atom, a chromium atom, an ironatom, a ruthenium atom, a cobalt atom, a rhodium atom, a nickel atom, apalladium atom, a samarium atom, and an ytterbium atom.

Examples of the above-mentioned cyclopentadiene-containing anionic groupof L are a cyclopentadienyl group, a substituent-having cyclopentadienylgroup, an indenyl group, a substituent-having indenyl group, a fluorenylgroup, and a substituent-having fluorenyl group.

Specific examples of the cyclopentadiene-containing anionic group are anη⁵-cyclopentadienyl group, an η⁵-methylcyclopentadienyl group, anη⁵-tert-butylcyclopentadienyl group, an η⁵-1,2-dimethylcyclopentadienylgroup, an η⁵-1,3-dimethylcyclopentadienyl group, anη⁵-1-tert-butyl-2-methylcyclopentadienyl group, anη⁵-1-tert-butyl-3-methylcyclopentadienyl group, anη⁵-1-methyl-2-isopropylcyclopentadienyl group, anη⁵-1-methyl-3-isopropylcyclopentadienyl group, an η⁵-1,2,3-trimethylcyclopentadienyl group, an η⁵-1,2,4-trimethylcyclopentadienyl group, anη⁵-tetramethylcyclopentadienyl group, an η⁵-pentamethylcyclopentadienylgroup, an η⁵-indenyl group, an η⁵-4,5,6,7-tetrahydroindenyl group, anη⁵-2-methylindenyl group, an η⁵-3-methylindenyl group, anη⁵-4-methylindenyl group, an η⁵-5-methylindenyl group, anη⁵-6-methylindenyl group, an η⁵-7-methylindenyl group, anη⁵-2-tert-butylindenyl group, an η⁵-3-tert-butylindenyl group, anη⁵-4-tert-butylindenyl group, an η⁵-5-tert-butylindenyl group, anη⁵-6-tert-butylindenyl group, an η⁵-7-tert-butylindenyl group, anη⁵-2,3-dimethylindenyl group, an η⁵-4,7-dimethylindenyl group, anη⁵-2,4,7-trimethylindenyl group, an η⁵-2-methyl-4-isopropylindenylgroup, an η⁵-4,5-benzindenyl group, an η⁵-2-methyl-4,5-benzindenylgroup, an η⁵-4-phenylindenyl group, an η⁵-2-methyl-5-phenylindenylgroup, an η⁵-2-methyl-4-phenylindenyl group, anη⁵-2-methyl-4-naphthylindenyl group, an η⁵-fluorenyl group, anη⁵-2,7-dimethylfluorenyl group, and an η⁵-2,7-di-tert-butylfluorenylgroup.

Examples of the hetero atom in the above-mentioned hetero atom-havinggroup of L are an oxygen atom, a sulfur atom, a nitrogen atom, and aphosphorus atom. Examples of the hetero atom-having group are an alkoxygroup; an aryloxy group; a thioalkoxy group; a thioaryloxy group; analkylamino group; an arylamino group; an alkylphosphino group; anarylphosphino group; an aromatic or aliphatic heterocyclic groupcontaining in its ring at least one atom selected from the groupconsisting of an oxygen atom, a sulfur atom, a nitrogen atom and aphosphorus atom; and a chelating ligand.

Examples of the hetero atom-having group are an alkoxy group such as amethoxy group, an ethoxy group, a propoxy group, and a butoxy group; anaryloxy group such as a phenoxy group, a 2-methylphenoxy group, a2,6-dimethylphenoxy group, a 2,4,6-trimethylphenoxy group, a2-ethylphenoxy group, a 4-n-propylphenoxy group, a 2-isopropylphenoxygroup, a 2,6-diisopropylphenoxy group, a 4-sec-butylphenoxy group, a4-tert-butylphenoxy group, a 2,6-di-sec-butylphenoxy group, a2-tert-butyl-4-methylphenoxy group, and a 2,6-di-tert-butylphenoxygroup; a substituent-having aryloxy group such as a 4-methoxyphenoxygroup, a 2,6-dimethoxyphenoxy group, a 3,5-dimethoxyphenoxy group, a2-chlorophenoxy group, a 4-nitrosophenoxy group, a 4-nitrophenoxy group,a 2-aminophenoxy group, a 3-aminophenoxy group, a 4-aminothiophenoxygroup, a 2,3,6-trichlorophenoxy group, and a 2,4,6-trifluorophenoxygroup; a thioalkoxy group such as a thiomethoxy group; an alkylaminogroup such as a dimethylamino group, a diethylamino group, adipropylamino group, an isopropylamino group, and a tert-butylaminogroup; an arylamino group such as a diphenylamino group; a pyrrolylgroup; a phosphino group such as a dimethylphosphino group; and aaryldioxy group such as a 2-(2-oxy-1-propyl)phenoxy group, a catecholatogroup, a resorcinolate group, a 4-isopropylcatecholato group, a3-methoxycatecholato group, a 1,8-dihydroxynahpthyl group, a1,2-dihydroxynahpthyl group, a 2,2′-biphenyldiol group, a1,1′-bi-2-naphthol group, a 2,2′-dihydroxy-6,6′-dimethylbiphenyl group,a 4,4′,6,6′-tetra-tert-butyl-2,2′-methylenediphenoxy group, and a4,4′,6,6′-tetramethyl-2,2′-isobutylidenediphenoxy group.

The above-mentioned chelating ligand in the examples of the heteroatom-having group means a ligand having plural coordinating positions.Examples thereof are acetylacetonate, diimine, oxazoline, bisoxazoline,terpyridine, acylhydrazone, diethylenetriamine, triethylenetetramine,porphyrin, crown ether and cryptate.

As mentioned above, when plural Ls exist, they may be linked (namely,plural cyclopentadiene-containing anionic groups may be linked; pluralhetero atom-having groups may be linked; or thecyclopentadiene-containing anionic group and the hetero atom-havinggroup may be linked) with one another directly or through a group havinga carbon atom, a silicon atom, a nitrogen atom, an oxygen atom, a sulfuratom or a phosphor atom. Examples of the group having a carbon atom, asilicon atom, a nitrogen atom, an oxygen atom, a sulfur atom or aphosphor atom are an alkylene group such as an ethylene group and apropylene group; a substituent-having alkylene group such as adimethylmethylene group (an isopropylidene group) and adiphenylmethylene group; a silylene group; a substituent-having silylenegroup such as a dimethylsilylene group, a diphenylsilylene group, and atetramethyldisilylene group; and a hetero-atom such as a nitrogen atom,an oxygen atom, a sulfur atom and a phosphorus atom.

Examples of the halogen atom of X¹ in formula (4) are a fluorine atom, achlorine atom, a bromine atom and an iodine atom, and examples of thehydrocarbyl group having 1 to 20 carbon atoms of X¹ therein are a methylgroup, an ethyl group, a n-propyl group, an isopropyl group, a n-butylgroup, a phenyl group, and a benzyl group.

Each number of “a” and “b” in formula (4) is determined so that thecharge of the transition metal compound represented by formula (4) isneutral, taking account of each valence of M¹, L and X¹.

Examples of the transition metal compound represented by formula (4),wherein M¹ is a titanium atom, are bis(cyclopentadienyl)titaniumdichloride, bis(methylcyclopentadienyl)titanium dichloride,bis(n-butylcyclopentadienyl)titanium dichloride,bis(dimethylcyclopentadienyl)titanium dichloride,bis(ethylmethylcyclopentadienyl)titanium dichloride,bis(trimethylcyclopentadienyl)titanium dichloride,bis(tetramethylcyclopentadienyl)titanium dichloride,bis(pentamethylcyclopentadienyl)titanium dichloride,bis(indenyl)titanium dichloride, bis(4,5,6,7-tetrahydroindenyl)titaniumdichloride, bis(fluorenyl)titanium dichloride,cyclopentadienyl(pentamethylcyclopentadienyl)titanium dichloride,cyclopentadienyl(indenyl)titanium dichloride,cyclopentadienyl(fluorenyl)titanium dichloride,indenyl(fluorenyl)titanium dichloride,pentamethylcyclopentadienyl(indenyl)titanium dichloride,pentamethylcyclopentadienyl(fluorenyl)titanium dichloride,ethylenebis(cyclopentadienyl)titanium dichloride,ethylenebis(2-methylcyclopentadienyl)titanium dichloride,ethylenebis(3-methylcyclopentadienyl)titanium dichloride,ethylenebis(2-n-butylcyclopentadienyl)titanium dichloride,ethylenebis(3-n-butylcyclopentadienyl)titanium dichloride,ethylenebis(2,3-dimethylcyclopentadienyl)titanium dichloride,ethylenebis(2,4-dimethylcyclopentadienyl)titanium dichloride,ethylenebis(2,5-dimethylcyclopentadienyl)titanium dichloride,ethylenebis(3,4-dimethylcyclopentadienyl)titanium dichloride,ethylenebis(2-ethyl-3-methylcyclopentadienyl)titanium dichloride,ethylenebis(2-ethyl-4-methylcyclopentadienyl)titanium dichloride,ethylenebis(2-ethyl-5-methylcyclopentadienyl)titanium dichloride,ethylenebis(3-ethyl-5-methylcyclopentadienyl)titanium dichloride,ethylenebis(2,3,4-trimethylcyclopentadienyl)titanium dichloride,ethylenebis(2,3,5-trimethylcyclopentadienyl)titanium dichloride,ethylenebis(tetramethylcyclopentadienyl)titanium dichloride,ethylenebis(indenyl)titanium dichloride,ethylenebis(4,5,6,7-tetrahydroindenyl)titanium dichloride,ethylenebis(2-phenylindenyl)titanium dichloride,ethylenebis(2-methylindenyl)titanium dichloride,ethylenebis(2-methyl-4-phenylindenyl)titanium dichloride,ethylenebis(2-methyl-4-naphthylindenyl)titanium dichloride,ethylenebis(2-methyl-4,5-benzoindenyl)titanium dichloride,ethylenebis(fluorenyl)titanium dichloride,ethylene(cyclopentadienyl)(pentamethylcyclopentadienyl)titaniumdichloride, ethylene(cyclopentadienyl)(indenyl)titanium dichloride,ethylene(methylcyclopentadienyl)(indenyl)titanium dichloride,ethylene(n-butylcyclopentadienyl)(indenyl)titanium dichloride,ethylene(tetramethylcyclopentadienyl)(indenyl)titanium dichloride,ethylene(cyclopentadienyl)(fluorenyl)titanium dichloride,ethylene(methylcyclopentadienyl)(fluorenyl)titanium dichloride, ethylene(pentamethylcyclopentadienyl)(fluorenyl)titanium dichloride,ethylene(n-butylcyclopentadienyl)(fluorenyl)titanium dichloride,ethylene (tetramethylpentadienyl)(fluorenyl)titanium dichloride,ethylene(indenyl)(fluorenyl)titanium dichloride,isopropylidenebis(cyclopentadienyl)titanium dichloride,isopropylidenebis(2-methylcyclopentadienyl)titanium dichloride,isopropylidenebis(3-methylcyclopentadienyl)titanium dichloride,isopropylidenebis(2-n-butylcyclopentadienyl)titanium dichloride,isopropylidenebis(3-n-butylcyclopentadienyl)titanium dichloride,isopropylidenebis(2,3-dimethylcyclopentadienyl) titanium dichloride,isopropylidenebis(2,4-dimethylcyclopentadienyl)titanium dichloride,isopropylidenebis(2,5-dimethylcyclopentadienyl) titanium dichloride,isopropylidenebis(3,4-dimethylcyclopentadienyl)titanium dichloride,isopropylidenebis(2-ethyl-3-methylcyclopentadienyl)titanium dichloride,isopropylidenebis(2-ethyl-4-methylcyclopentadienyl)titanium dichloride,isopropylidenebis(2-ethyl-5-methylcyclopentadienyl)titanium dichloride,isopropylidenebis(3-ethyl-5-methylcyclopentadienyl)titanium dichloride,isopropylidenebis(2,3,4-trimethylcyclopentadienyl)titanium dichloride,isopropylidenebis(2,3,5-trimethylcyclopentadienyl)titanium dichloride,isopropylidenebis(tetramethylcyclopentadienyl) titanium dichloride,isopropylidenebis(indenyl)titanium dichloride,isopropylidenebis(4,5,6,7-tetrahydroindenyl)titanium dichloride,isopropylidenebis(2-phenylindenyl)titanium dichloride,isopropylidenebis(2-methylindenyl)titanium dichloride,isopropylidenebis(2-methyl-4-phenylindenyl)titanium dichloride,isopropylidenebis(2-methyl-4-naphthylindenyl)titanium dichloride,isopropylidenebis(2-methyl-4,5-benzoindenyl)titanium dichloride,isopropylidenebis(fluorenyl)titanium dichloride,isopropylidene(cyclopentadienyl)(tetramethylcyclopentadienyl)titaniumdichloride, isopropylidene(cyclopentadienyl)(indenyl)titaniumdichloride, isopropylidene(methylcyclopentadienyl)(indenyl)titaniumdichloride, isopropylidene(n-butylcyclopentadienyl)(indenyl) titaniumdichloride, isopropylidene(tetramethylcyclopentadienyl)(indenyl)titaniumdichloride, isopropylidene (cyclopentadienyl)(fluorenyl)titaniumdichloride, isopropylidene(methylcyclopentadienyl)(fluorenyl)titaniumdichloride, isopropylidene(n-butylcyclopentadienyl)(fluorenyl)titaniumdichloride,isopropylidene(tetramethylcyclopentadienyl)(fluorenyl)titaniumdichloride, isopropylidene (indenyl)(fluorenyl)titanium dichloride,dimethylsilylenebis(cyclopentadienyl)titanium dichloride,dimethylsilylenebis(2-methylcyclopentadienyl)titanium dichloride,dimethylsilylenebis(3-methylcyclopentadienyl) titanium dichloride,dimethylsilylenebis(2-n-butylcyclopentadienyl)titanium dichloride,dimethylsilylenebis(3-n-butylcyclopentadienyl) titanium dichloride,dimethylsilylenebis(2,3-dimethylcyclopentadienyl)titanium dichloride,dimethylsilylenebis(2,4-dimethylcyclopentadienyl) titanium dichloride,dimethylsilylenebis(2,5-dimethylcyclopentadienyl)titanium dichloride,dimethylsilylenebis(3,4-dimethylcyclopentadienyl) titanium dichloride,dimethylsilylenebis(2-ethyl-3-methylcyclopentadienyl) titaniumdichloride, dimethylsilylenebis(2-ethyl-4-methylcyclopentadienyl)titanium dichloride,dimethylsilylenebis(2-ethyl-5-methylcyclopentadienyl) titaniumdichloride, dimethylsilylenebis(3-ethyl-5-methylcyclopentadienyl)titanium dichloride,dimethylsilylenebis(2,3,4-trimethylcyclopentadienyl) titaniumdichloride, dimethylsilylenebis(2,3,5-trimethylcyclopentadienyl)titanium dichloride,dimethylsilylenebis(tetramethylcyclopentadienyl)titanium dichloride,dimethylsilylenebis(indenyl)titanium dichloride,dimethylsilylenebis(4,5,6,7-tetrahydroindenyl)titanium dichloride,dimethylsilylenebis(2-phenylindenyl)titanium dichloride,dimethylsilylenebis(2-methylindenyl)titanium dichloride,dimethylsilylenebis(2-methyl-4-phenylindenyl) titanium dichloride,dimethylsilylenebis(2-methyl-4-naphthylindenyl)titanium dichloride,dimethylsilylenebis(2-methyl-4,5-benzoindenyl) titanium dichloride,dimethylsilylene(cyclopentadienyl)(indenyl)titanium dichloride,dimethylsilylene(methylcyclopentadienyl)(indenyl)titanium dichloride,dimethylsilylene(n-butylcyclopentadienyl)(indenyl)titanium dichloride,dimethylsilylene(tetramethylcyclopentadienyl)(indenyl)titaniumdichloride, dimethylsilylene(cyclopentadienyl)(fluorenyl)titaniumdichloride, dimethylsilylene(methylcyclopentadienyl)(fluorenyl) titaniumdichloride, dimethylsilylene(n-butylcyclopentadienyl)(fluorenyl)titanium dichloride,dimethylsilylene(tetramethylcyclopentadienyl)(indenyl) titaniumdichloride, dimethylsilylene(indenyl)(fluorenyl)titanium dichloride,cyclopentadienylitanium trichloride, pentamethylcyclopentadienyltitaniumtrichloride, cyclopentadienyl(dimethylamido)titanium dichloride,cyclopentadienyl(phenoxy)titanium dichloride,cyclopentadienyl(2,6-dimethylphenyl)titanium dichloride,cyclopentadienyl(2,6-diisopropylphenyl)titanium dichloride,cyclopentadienyl(2,6-di-tert-butylphenyl)titanium dichloride,pentamethylcyclopentadienyl(2,6-dimethylphenyl)titanium dichloride,pentamethylcyclopentadienyl(2,6-diisopropylphenyl)titanium dichloride,pentamethylcyclopentadienyl(2,6-di-tert-butylphenyl) titaniumdichloride, indenyl(2,6-diisopropylphenyl)titanium dichloride, fluorenyl(2,6-diisopropylphenyl)titanium dichloride,methylene(cyclopentadienyl)(3,5-dimethyl-2-phenoxy)titanium dichloride,methylene(cyclopentadienyl)(3-tert-butyl-2-phenoxy)titanium dichloride,methylene(cyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride, methylene(cyclopentadienyl)(3-phenyl-2-phenoxy)titaniumdichloride,methylene(cyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,methylene(cyclopentadienyl)(3-trimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,methylene(cyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy) titaniumdichloride,methylene(cyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride, methylene(methylcyclopentadienyl)(3,5-dimethyl-2-phenoxy)titanium dichloride,methylene(methylcyclopentadienyl)(3-tert-butyl-2-phenoxy) titaniumdichloride,methylene(methylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride, methylene(methylcyclopentadienyl)(3-phenyl-2-phenoxy)titanium dichloride,methylene(methylcyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,methylene(methylcyclopentadienyl)(3-trimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,methylene(methylcyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,methylene(methylcyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride,methylene(tert-butylcyclopentadienyl)(3,5-dimethyl-2-phenoxy)titaniumdichloride,methylene(tert-butylcyclopentadienyl)(3-tert-butyl-2-phenoxy)titaniumdichloride,methylene(tetr-butylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride, methylene(tetr-butylcyclopentadienyl)(3-phenyl-2-phenoxy)titanium dichloride,methylene(tetr-butylcyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,methylene(tetr-butylcyclopentadienyl)(3-trimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,methylene(tetr-butylcyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,methylene(tetr-butylcyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride,methylene(tetramethylcyclopentadienyl)(3,5-dimethyl-2-phenoxy)titaniumdichloride,methylene(tetramethylcyclopentadienyl)(3-tert-butyl-2-phenoxy)titaniumdichloride,methylene(tetramethylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride, methylene(tetramethylcyclopentadienyl)(3-phenyl-2-phenoxy)titanium dichloride,methylene(tetramethylcyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,methylene(tetramethylcyclopentadienyl)(3-trimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,methylene(tetramethylcyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,methylene(tetramethylcyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride,methylene(trimethylsilylcyclopentadienyl)(3,5-dimethyl-2-phenoxy)titaniumdichloride,methylene(trimethylsilylcyclopentadienyl)(3-tert-butyl-2-phenoxy)titaniumdichloride,methylene(trimethylsilylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride,methylene(trimethylsilylcyclopentadienyl)(3-phenyl-2-phenoxy)titaniumdichloride,methylene(trimethylsilylcyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,methylene(trimethylsilylcyclopentadienyl)(3-trimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,methylene(trimethylsilylcyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,methylene(trimethylsilylcyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride, methylene(fluorenyl)(3,5-dimethyl-2-phenoxy)titaniumdichloride, methylene(fluorenyl)(3-tert-butyl-2-phenoxy)titaniumdichloride, methylene(fluorenyl)(3-tert-butyl-5-methyl-2-phenoxy)titanium dichloride, methylene(fluorenyl)(3-phenyl-2-phenoxy)titaniumdichloride,methylene(fluorenyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride, methylene(fluorenyl)(3-trimethylsilyl-5-methyl-2-phenoxy)titanium dichloride,methylene(fluorenyl)(3-tert-butyl-5-methoxy-2-phenoxy) titaniumdichloride, methylene(fluorenyl)(3-tert-butyl-5-chloro-2-phenoxy)titanium dichloride,isopropylidene(cyclopentadienyl)(3,5-dimethyl-2-phenoxy) titaniumdichloride, isopropylidene(cyclopentadienyl)(3-tert-butyl-2-phenoxy)titanium dichloride,isopropylidene(cyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride, isopropylidene(cyclopentadienyl)(3-phenyl-2-phenoxy)titanium dichloride,isopropylidene(cyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,isopropylidene(cyclopentadienyl)(3-trimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,isopropylidene(cyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,isopropylidene(cyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride,isopropylidene(methylcyclopentadienyl)(3,5-dimethyl-2-phenoxy)titaniumdichloride,isopropylidene(methylcyclopentadienyl)(3-tert-butyl-2-phenoxy)titaniumdichloride,isopropylidene(methylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride, isopropylidene(methylcyclopentadienyl)(3-phenyl-2-phenoxy)titanium dichloride,isopropylidene(methylcyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,isopropylidene(methylcyclopentadienyl)(3-trimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,isopropylidene(methylcyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,isopropylidene(methylcyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride,isopropylidene(tert-butylcyclopentadienyl)(3,5-dimethyl-2-phenoxy)titaniumdichloride,isopropylidene(tert-butylcyclopentadienyl)(3-tert-butyl-2-phenoxy)titaniumdichloride,isopropylidene(tert-butylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride,isopropylidene(tert-butylcyclopentadienyl)(3-phenyl-2-phenoxy)titaniumdichloride,isopropylidene(tert-butylcyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,isopropylidene(tert-butylcyclopentadienyl)(3-trimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,isopropylidene(tert-butylcyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,isopropylidene(tert-butylcyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride,isopropylidene(tetramethylcyclopentadienyl)(3,5-dimethyl-2-phenoxy)titaniumdichloride,isopropylidene(tetramethylcyclopentadienyl)(3-tert-butyl-2-phenoxy)titaniumdichloride,isopropylidene(tetramethylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride,isopropylidene(tetramethylcyclopentadienyl)(3-phenyl-2-phenoxy)titaniumdichloride,isopropylidene(tetramethylcyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,isopropylidene(tetramethylcyclopentadienyl)(3-trimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,isopropylidene(tetramethylcyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,isopropylidene(tetramethylcyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride,isopropylidene(trimethylsilylcyclopentadienyl)(3,5-dimethyl-2-phenoxy)titaniumdichloride,isopropylidene(trimethylsilylcyclopentadienyl)(3-tert-butyl-2-phenoxy)titaniumdichloride,isopropylidene(trimethylsilylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride,isopropylidene(trimethylsilylcyclopentadienyl)(3-phenyl-2-phenoxy)titaniumdichloride,isopropylidene(trimethylsilylcyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,isopropylidene(trimethylsilylcyclopentadienyl)(3-trimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,isopropylidene(trimethylsilylcyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,isopropylidene(trimethylsilylcyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride, isopropylidene(fluorenyl)(3,5-dimethyl-2-phenoxy)titaniumdichloride, isopropylidene(fluorenyl)(3-tert-butyl-2-phenoxy)titaniumdichloride, isopropylidene(fluorenyl)(3-tert-butyl-5-methyl-2-phenoxy)titanium dichloride,isopropylidene(fluorenyl)(3-phenyl-2-phenoxy)titanium dichloride,isopropylidene(fluorenyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,isopropylidene(fluorenyl)(3-trimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride, isopropylidene(fluorenyl)(3-tert-butyl-5-methoxy-2-phenoxy)titanium dichloride,isopropylidene(fluorenyl)(3-tert-butyl-5-chloro-2-phenoxy) titaniumdichloride, diphenylmethylene(cyclopentadienyl)(3,5-dimethyl-2-phenoxy)titanium dichloride,diphenylmethylene(cyclopentadienyl)(3-tert-butyl-2-phenoxy) titaniumdichloride,diphenylmethylene(cyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride, diphenylmethylene(cyclopentadienyl)(3-phenyl-2-phenoxy)titanium dichloride,diphenylmethylene(cyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,diphenylmethylene(cyclopentadienyl)(3-trimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,diphenylmethylene(cyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,diphenylmethylene(cyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride,diphenylmethylene(methylcyclopentadienyl)(3,5-dimethyl-2-phenoxy)titaniumdichloride,diphenylmethylene(methylcyclopentadienyl)(3-tert-butyl-2-phenoxy)titaniumdichloride,diphenylmethylene(methylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride,diphenylmethylene(methylcyclopentadienyl)(3-phenyl-2-phenoxy)titaniumdichloride,diphenylmethylene(methylcyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,diphenylmethylene(methylcyclopentadienyl)(3-trimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,diphenylmethylene(methylcyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,diphenylmethylene(methylcyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride,diphenylmethylene(tert-butylcyclopentadienyl)(3,5-dimethyl-2-phenoxy)titaniumdichloride,diphenylmethylene(tert-butylcyclopentadienyl)(3-tert-butyl-2-phenoxy)titaniumdichloride,diphenylmethylene(tert-butylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride,diphenylmethylene(tert-butylcyclopentadienyl)(3-phenyl-2-phenoxy)titaniumdichloride,diphenylmethylene(tert-butylcyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,diphenylmethylene(tert-butylcyclopentadienyl)(3-trimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,diphenylmethylene(tert-butylcyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,diphenylmethylene(tert-butylcyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride,diphenylmethylene(tetramethylcyclopentadienyl)(3,5-dimethyl-2-phenoxy)titaniumdichloride,diphenylmethylene(tetramethylcyclopentadienyl)(3-tert-butyl-2-phenoxy)titaniumdichloride,diphenylmethylene(tetramethylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride,diphenylmethylene(tetramethylcyclopentadienyl)(3-phenyl-2-phenoxy)titaniumdichloride,diphenylmethylene(tetramethylcyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,diphenylmethylene(tetramethylcyclopentadienyl)(3-trimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,diphenylmethylene(tetramethylcyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,diphenylmethylene(tetramethylcyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride,diphenylmethylene(trimethylsilylcyclopentadienyl)(3,5-dimethyl-2-phenoxy)titaniumdichloride,diphenylmethylene(trimethylsilylcyclopentadienyl)(3-tert-butyl-2-phenoxy)titaniumdichloride,diphenylmethylene(trimethylsilylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride,diphenylmethylene(trimethylsilylcyclopentadienyl)(3-phenyl-2-phenoxy)titaniumdichloride,diphenylmethylene(trimethylsilylcyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,diphenylmethylene(trimethylsilylcyclopentadienyl)(3-trimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,diphenylmethylene(trimethylsilylcyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,diphenylmethylene(trimethylsilylcyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride, diphenylmethylene(fluorenyl)(3,5-dimethyl-2-phenoxy)titanium dichloride,diphenylmethylene(fluorenyl)(3-tert-butyl-2-phenoxy) titaniumdichloride,diphenylmethylene(fluorenyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride, diphenylmethylene(fluorenyl)(3-phenyl-2-phenoxy)titaniumdichloride,diphenylmethylene(fluorenyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,diphenylmethylene(fluorenyl)(3-trimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,diphenylmethylene(fluorenyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,diphenylmethylene(fluorenyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride, dimethylsilylene(cyclopentadienyl)(2-phenoxy)titaniumdichloride, dimethylsilylene(cyclopentadienyl)(3-methyl-2-phenoxy)titanium dichloride,dimethylsilylene(cyclopentadienyl)(3,5-dimethyl-2-phenoxy) titaniumdichloride, dimethylsilylene(cyclopentadienyl)(3-tert-butyl-2-phenoxy)titanium dichloride,dimethylsilylene(cyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride,dimethylsilylene(cyclopentadienyl)(3,5-di-tert-butyl-2-phenoxy)titaniumdichloride,dimethylsilylene(cyclopentadienyl)(5-methyl-3-phenyl-2-phenoxy)titaniumdichloride,dimethylsilylene(cyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,dimethylsilylene(cyclopentadienyl)(5-methyl-3-trimethylsilyl-2-phenoxy)titaniumdichloride,dimethylsilylene(cyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,dimethylsilylene(cyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride, dimethylsilylene(cyclopentadienyl)(3,5-diamyl-2-phenoxy)titanium dichloride,dimethylsilylene(methylcyclopentadienyl)(2-phenoxy)titanium dichloride,dimethylsilylene(methylcyclopentadienyl)(3-methyl-2-phenoxy)titaniumdichloride,dimethylsilylene(methylcyclopentadienyl)(3,5-dimethyl-2-phenoxy)titaniumdichloride,dimethylsilylene(methylcyclopentadienyl)(3-tert-butyl-2-phenoxy)titaniumdichloride,dimethylsilylene(methylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride,dimethylsilylene(methylcyclopentadienyl)(3,5-di-tert-butyl-2-phenoxy)titaniumdichloride,dimethylsilylene(methylcyclopentadienyl)(5-methyl-3-phenyl-2-phenoxy)titaniumdichloride,dimethylsilylene(methylcyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,dimethylsilylene(methylcyclopentadienyl)(5-methyl-3-trimethylsilyl-2-phenoxy)titaniumdichloride,dimethylsilylene(methylcyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,dimethylsilylene(methylcyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride,dimethylsilylene(methylcyclopentadienyl)(3,5-diamyl-2-phenoxy)titaniumdichloride, dimethylsilylene(n-butylcyclopentadienyl)(2-phenoxy)titanium dichloride,dimethylsilylene(n-butylcyclopentadienyl)(3-methyl-2-phenoxy)titaniumdichloride,dimethylsilylene(n-butylcyclopentadienyl)(3,5-dimethyl-2-phenoxy)titaniumdichloride,dimethylsilylene(n-butylcyclopentadienyl)(3-tert-butyl-2-phenoxy)titaniumdichloride,dimethylsilylene(n-butylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride,dimethylsilylene(n-butylcyclopentadienyl)(3,5-di-tert-butyl-2-phenoxy)titaniumdichloride,dimethylsilylene(n-butylcyclopentadienyl)(5-methyl-3-phenyl-2-phenoxy)titaniumdichloride,dimethylsilylene(n-butylcyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,dimethylsilylene(n-butylcyclopentadienyl)(5-methyl-3-trimethylsilyl-2-phenoxy)titaniumdichloride,dimethylsilylene(n-butylcyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,dimethylsilylene(n-butylcyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride,dimethylsilylene(n-butylcyclopentadienyl)(3,5-diamyl-2-phenoxy)titaniumdichloride, dimethylsilylene(tert-butylcyclopentadienyl)(2-phenoxy)titanium dichloride,dimethylsilylene(tert-butylcyclopentadienyl)(3-methyl-2-phenoxy)titaniumdichloride,dimethylsilylene(tert-butylcyclopentadienyl)(3,5-dimethyl-2-phenoxy)titaniumdichloride,dimethylsilylene(tert-butylcyclopentadienyl)(3-tert-butyl-2-phenoxy)titaniumdichloride,dimethylsilylene(tert-butylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titanium dichloride,dimethylsilylene(tert-butylcyclopentadienyl)(3,5-di-tert-butyl-2-phenoxy)titaniumdichloride,dimethylsilylene(tert-butylcyclopentadienyl)(5-methyl-3-phenyl-2-phenoxy)titaniumdichloride,dimethylsilylene(tert-butylcyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,dimethylsilylene(tert-butylcyclopentadienyl)(5-methyl-3-trimethylsilyl-2-phenoxy)titaniumdichloride,dimethylsilylene(tert-butylcyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titanium dichloride,dimethylsilylene(tert-butylcyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride,dimethylsilylene(tert-butylcyclopentadienyl)(3,5-diamyl-2-phenoxy)titaniumdichloride, dimethylsilylene(tetramethylcyclopentadienyl)(2-phenoxy)titanium dichloride,dimethylsilylene(tetramethylcyclopentadienyl)(3-methyl-2-phenoxy)titaniumdichloride,dimethylsilylene(tetramethylcyclopentadienyl)(3,5-dimethyl-2-phenoxy)titaniumdichloride,dimethylsilylene(tetramethylcyclopentadienyl)(3-tert-butyl-2-phenoxy)titaniumdichloride,dimethylsilylene(tetramethylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride,dimethylsilylene(tetramethylcyclopentadienyl)(3,5-di-tert-butyl-2-phenoxy)titaniumdichloride,dimethylsilylene(tetramethylcyclopentadienyl)(5-methyl-3-phenyl-2-phenoxy)titaniumdichloride,dimethylsilylene(tetramethylcyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,dimethylsilylene(tetramethylcyclopentadienyl)(5-methyl-3-trimethylsilyl-2-phenoxy)titaniumdichloride,dimethylsilylene(tetramethylcyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,dimethylsilylene(tetramethylcyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride,dimethylsilylene(tetramethylcyclopentadienyl)(3,5-diamyl-2-phenoxy)titaniumdichloride, dimethylsilylene(trimethylsilylcyclopentadienyl)(2-phenoxy)titanium dichloride,dimethylsilylene(trimethylsilylcyclopentadienyl)(3-methyl-2-phenoxy)titaniumdichloride,dimethylsilylene(trimethylsilylcyclopentadienyl)(3,5-dimethyl-2-phenoxy)titaniumdichloride,dimethylsilylene(trimethylsilylcyclopentadienyl)(3-tert-butyl-2-phenoxy)titaniumdichloride,dimethylsilylene(trimethylsilylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride,dimethylsilylene(trimethylsilylcyclopentadienyl)(3,5-di-tert-butyl-2-phenoxy)titaniumdichloride,dimethylsilylene(trimethylsilylcyclopentadienyl)(5-methyl-3-phenyl-2-phenoxy)titaniumdichloride,dimethylsilylene(trimethylsilylcyclopentadienyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,dimethylsilylene(trimethylsilylcyclopentadienyl)(5-methyl-3-trimethylsilyl-2-phenoxy)titaniumdichloride,dimethylsilylene(trimethylsilylcyclopentadienyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,dimethylsilylene(trimethylsilylcyclopentadienyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride,dimethylsilylene(trimethylsilylcyclopentadienyl)(3,5-diamyl-2-phenoxy)titaniumdichloride, dimethylsilylene(indenyl)(2-phenoxy)titanium dichloride,dimethylsilylene(indenyl)(3-methyl-2-phenoxy)titanium dichloride,dimethylsilylene(indenyl)(3,5-dimethyl-2-phenoxy)titanium dichloride,dimethylsilylene(indenyl)(3-tert-butyl-2-phenoxy)titanium dichloride,dimethylsilylene(indenyl)(3-tert-butyl-5-methyl-2-phenoxy) titaniumdichloride, dimethylsilylene(indenyl)(3,5-di-tert-butyl-2-phenoxy)titanium dichloride,dimethylsilylene(indenyl)(5-methyl-3-phenyl-2-phenoxy)titaniumdichloride,dimethylsilylene(indenyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,dimethylsilylene(indenyl)(5-methyl-3-trimethylsilyl-2-phenoxy)titaniumdichloride, dimethylsilylene(indenyl)(3-tert-butyl-5-methoxy-2-phenoxy)titanium dichloride,dimethylsilylene(indenyl)(3-tert-butyl-5-chloro-2-phenoxy) titaniumdichloride, dimethylsilylene(indenyl)(3,5-diamyl-2-phenoxy)titaniumdichloride, dimethylsilylene(fluorenyl)(2-phenoxy)titanium dichloride,dimethylsilylene(fluorenyl)(3-methyl-2-phenoxy)titanium dichloride,dimethylsilylene(fluorenyl)(3,5-dimethyl-2-phenoxy)titanium dichloride,dimethylsilylene(fluorenyl)(3-tert-butyl-2-phenoxy)titanium dichloride,dimethylsilylene(fluorenyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumdichloride, dimethylsilylene(fluorenyl)(3,5-di-tert-butyl-2-phenoxy)titanium dichloride,dimethylsilylene(fluorenyl)(5-methyl-3-phenyl-2-phenoxy)titaniumdichloride,dimethylsilylene(fluorenyl)(3-tert-butyldimethylsilyl-5-methyl-2-phenoxy)titaniumdichloride,dimethylsilylene(fluorenyl)(5-methyl-3-trimethylsilyl-2-phenoxy)titaniumdichloride,dimethylsilylene(fluorenyl)(3-tert-butyl-5-methoxy-2-phenoxy)titaniumdichloride,dimethylsilylene(fluorenyl)(3-tert-butyl-5-chloro-2-phenoxy)titaniumdichloride, dimethylsilylene(fluorenyl)(3,5-diamyl-2-phenoxy)titaniumdichloride, anddimethylsilylene(tetramethylcyclopentadienyl)(1-naphthoxy-2-yl)titaniumdichloride; compounds obtained by replacing the term “(2-phenoxy)” ofthose compounds with the term “(3-phenyl-2-phenoxy)”,“(3-trimethylsilyl-2-phenoxy)” or“(3-tert-butyldimethylsilyl-2-phenoxy)”; compounds obtained by replacingthe term “dimethylsilylene” of those compounds with the term“diethylsilylene”, “diphenylsilylene” or “dimethoxysilylene”; andcompounds obtained by replacing the term “dichloride” of those compoundswith the term “difluoride”, “dibromide”, “diiodide”, “dimethyl”,“diethyl”, “diisopropyl”, “bis(dimethylamido)”, “bis(diethylamido)”,“dimethoxide”, “diethoxide”, “di-n-butoxide” or “diisopropoxide”.

Further examples of the transition metal compound represented by formula(4), wherein M¹ is a titanium atom, are(tert-butylamido)tetramethylcyclopentadienyl-1,2-ethanediyltitaniumdichloride,(tert-butylamido)tetramethylcyclopentadienyl-1,2-ethanediyltitaniumdimethyl,(tert-butylamido)tetramethylcyclopentadienyl-1,2-ethanediyltitaniumdibenzyl,(methylamido)tetramethylcyclopentadienyl-1,2-ethanediyltitaniumdichloride,(ethylamido)tetramethylcyclopentadienyl-1,2-ethanediyltitaniumdichloride, (tert-butylamido)tetramethylcyclopentadienyldimethylsilanetitanium dichloride,(tert-butylamido)tetramethylcyclopentadienyl dimethylsilanetitaniumdimethyl, (tert-butylamido)tetramethylcyclopentadienyldimethylsilanetitanium dibenzyl,(benzylamido)tetramethylcyclopentadienyl dimethylsilanetitaniumdichloride, (phenylphosphido)tetramethylcyclopentadienyldimethylsilanetitanium dibenzyl,(tert-butylamido)indenyl-1,2-ethanediyltitanium dichloride,(tert-butylamido)indenyl-1,2-ethanediyltitanium dimethyl,(tert-butylamido)tetrahydroindenyl-1,2-ethanediyl titanium dichloride,(tert-butylamido)tetrahydroindenyl-1,2-ethanediyl titanium dimethyl,(tert-butylamido)fluorenyl-1,2-ethanediyltitanium dichloride,(tert-butylamido)fluorenyl-1,2-ethanediyltitanium dimethyl,(tert-butylamido)indenyldimethylsilanetitanium dichloride,(tert-butylamido)indenyldimethylsilanetitanium dimethyl,(tert-butylamido)tetrahydroindenyldimethylsilane titanium dichloride,(tert-butylamido)tetrahydroindenyldimethylsilane titanium dimethyl,(tert-butylamido)fluorenyldimethylsilanetitanium dichloride,(tert-butylamido)fluorenyldimethylsilanetitanium dimethyl,(dimethylaminomethyl)tetramethylcyclopentadienyl titanium(III)dichloride, (dimethylaminoethyl)tetramethylcyclopentadienyltitanium(III) dichloride,(dimethylaminopropyl)tetramethylcyclopentadienyl titanium(III)dichloride, (N-pyrrolidinylethyl)tetramethylcyclopentadienyl titaniumdichloride, (B-dimethylaminoborabenzene)cyclopentadienylzirconiumdichloride, cyclopentadienyl(9-mesitylboraanthracenyl)zirconiumdichloride, 2,2′-thiobis(4-methyl-6-tert-butylphenoxy)titaniumdichloride, 2,2′-thiobis[4-methyl-6-(1-methylethyl)phenoxy]titaniumdichloride, 2,2′-thiobis[4,6-dimethylphenoxy]titanium dichloride,2,2′-methylenebis(4-methyl-6-tert-butylphenoxy) titanium dichloride,2,2′-ethylenebis(4-methyl-6-tert-butylphenoxy)titanium dichloride,2,2′-sulfinylbis(4-methyl-6-tert-butylphenoxy) titanium dichloride,2,2′-(4,4′,6,6′-tetra-tert-butyl-1,1′-biphenoxy)titanium dichloride,2,2′-thiobis[4-methyl-6-tert-butylphenoxy]titanium diisopropoxide,2,2′-methylenebis(4-methyl-6-tert-butylphenoxy)titanium diisopropoxide,2,2′-ethylenebis(4-methyl-6-tert-butylphenoxy)titanium diisopropoxide,2,2′-sulfinylbis(4-methyl-6-tert-butylphenoxy)titanium diisopropoxide,(di-tert-butyl-1,3-propanediamido)titanium dichloride,(dicyclohexyl-1,3-propanediamido)titanium dichloride,[bis(trimethylsilyl)-1,3-propanediamido]titanium dichloride,[bis(tert-butyldimethylsilyl)-1,3-propanediamido]titanium dichloride,[bis(2,6-dimethylphenyl)-1,3-propanediamido]titanium dichloride,[bis(2,6-diisopropylphenyl)-1,3-propanediamido]titanium dichloride,[bis(2,6-di-tert-butylphenyl)-1,3-propanediamido]titanium dichloride,[bis(triisopropylsilyl)naphthalenediamido]titanium dichloride,[bis(trimethylsilyl)naphthalenediamido]titanium dichloride,[bis(tert-butyldimethylsilyl)naphthalenediamido]titanium dichloride,[bis(tert-butyldimethylsilyl)naphthalenediamido]titanium dibromide,[hydrotris(3,5-dimethylpyrazolyl)borate]titanium trichloride,[hydrotris(3,5-dimethylpyrazolyl)borate]titanium tribromide,[hydrotris(3,5-dimethylpyrazolyl)borate]titanium triiodide,[hydrotris(3,5-diethylpyrazolyl)borate]titanium trichloride,[hydrotris(3,5-diethylpyrazolyl)borate]titanium tribromide,[hydrotris(3,5-diethylpyrazolyl)borate]titanium triiodide,[hydrotris(3,5-di-tert-butylpyrazolyl)borate]titanium trichloride,[hydrotris(3,5-di-tert-butylpyrazolyl)borate]titanium tribromide,[hydrotris(3,5-di-tert-butylpyrazolyl)borate]titanium triiodide,[tris(3,5-dimethylpyrazolyl)methyl]titanium trichloride,[tris(3,5-dimethylpyrazolyl)methyl]titanium tribromide,[tris(3,5-dimethylpyrazolyl)methyl]titanium triiodide,[tris(3,5-diethylpyrazolyl)methyl]titanium trichloride,[tris(3,5-diethylpyrazolyl)methyl]titanium tribromide,[tris(3,5-diethylpyrazolyl)methyl]titanium triiodide,[tris(3,5-di-tert-butylpyrazolyl)methyl]titanium trichloride,[tris(3,5-di-tert-butylpyrazolyl)methyl]titanium tribromide,[tris(3,5-di-tert-butylpyrazolyl)methyl]titanium triiodide,μ-oxobis[isopropylidene(cyclopentadienyl)(2-phenoxy) titanium chloride],μ-oxobis[isopropylidene (cyclopentadienyl)(2-phenoxy)titaniummethoxide],μ-oxobis[isopropylidene(cyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumchloride], μ-oxobis[isopropylidene(cyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniummethoxide], μ-oxobis[isopropylidene(methylcyclopentadienyl)(2-phenoxy)titanium chloride],μ-oxobis[isopropylidene(methylcyclopentadienyl)(2-phenoxy) titaniummethoxide], μ-oxobis[isopropylidene(methylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy) titaniumchloride], μ-oxobis[isopropylidene(methylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy) titaniummethoxide], μ-oxobis[isopropylidene(tetramethylcyclopentadienyl)(2-phenoxy)titanium chloride],μ-oxobis[isopropylidene(tetramethylcyclopentadienyl) (2-phenoxy)titaniummethoxide], μ-oxobis[isopropylidene(tetramethylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniumchloride], μ-oxobis[isopropylidene(tetramethylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titaniummethoxide], μ-oxobis[dimethylsilylene(cyclopentadienyl)(2-phenoxy)titanium chloride],μ-oxobis[dimethylsilylene(cyclopentadienyl)(2-phenoxy) titaniummethoxide], μ-oxobis[dimethylsilylene(cyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titanium chloride],μ-oxobis[dimethylsilylene(cyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titanium methoxide],μ-oxobis[dimethylsilylene(methylcyclopentadienyl)(2-phenoxy) titaniumchloride], μ-oxobis[dimethylsilylene(methylcyclopentadienyl)(2-phenoxy)titanium methoxide],μ-oxobis[dimethylsilylene(methylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titanium chloride],μ-oxobis[dimethylsilylene(methylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titanium methoxide],μ-oxobis[dimethylsilylene(tetramethylcyclopentadienyl)(2-phenoxy)titanium chloride], μ-oxobis[dimethylsilylene(tetramethylcyclopentadienyl)(2-phenoxy)titanium methoxide],μ-oxobis[dimethylsilylene(tetramethylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titanium chloride],μ-oxobis[dimethylsilylene(tetramethylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titanium methoxide],di-μ-oxobis[isopropylidene(cyclopentadienyl)(2-phenoxy) titanium],di-μ-oxobis[isopropylidene(cyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titanium], di-μ-oxobis[isopropylidene(methylcyclopentadienyl)(2-phenoxy)titanium],di-μ-oxobis[isopropylidene(methylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titanium],di-μ-oxobis [isopropylidene(tetramethylcyclopentadienyl)(2-phenoxy)titanium], di-μ-oxobis[isopropylidene(tetramethylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titanium],di-μ-oxobis[dimethylsilylene (cyclopentadienyl)(2-phenoxy)titanium],di-μ-oxobis[dimethylsilylene(cyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titanium],di-μ-oxobis[dimethylsilylene(methylcyclopentadienyl)(2-phenoxy)titanium], di-μ-oxobis[dimethylsilylene(methylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titanium],di-μ-oxobis[dimethylsilylene(tetramethylcyclopentadienyl)(2-phenoxy)titanium], anddi-μ-oxobis[dimethylsilylene(tetramethylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)titanium].

Examples of the transition metal compound represented by formula (4),wherein M¹ is a zirconium atom or a hafnium atom, are compounds obtainedby replacing the term “titanium” of the above-exemplified titaniumcompounds with the term “zirconium” or “hafnium”.

Examples of the transition metal compound represented by formula (4),wherein M¹ is a vanadium atom, are vanadium acetylacetonate, vanadiumtetrachloride and vanadium oxy trichloride.

An example of the transition metal compound represented by formula (4),wherein M¹ is a samarium atom, isbis(pentamethylcyclopentadienyl)samarium methyltetrahydrofuran.

An example of the transition metal compound represented by formula (4),wherein M¹ is an ytterbium atom, isbis(pentamethylcyclopentadienyl)ytterbium methyltetrahydrofuran.

Examples of the transition metal compound represented by formula (4),wherein M¹ is a palladium atom, are2,2′-methylenebis[(4R)-4-phenyl-5,5′-dimethyloxazoline]palladiumdichloride,2,2′-methylenebis[(4R)-4-phenyl-5,5′-dimethyloxazoline]palladiumdibromide, 2,2′-methylenebis[(4R)-4-phenyl-5,5′-diethyloxazoline]palladium dichloride,2,2′-methylenebis[(4R)-4-phenyl-5,5′-diethyloxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-phenyl-5,5′-di-n-propyloxazoline]palladiumdichloride,2,21-methylenebis[(4R)-4-phenyl-5,5′-di-n-propyloxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-phenyl-5,5′-diisopropyloxazoline]palladiumdichloride,2,21-methylenebis[(4R)-4-phenyl-5,51-diisopropyloxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-phenyl-5,5′-dicyclohexyloxazoline]palladiumdichloride,2,2′-methylenebis[(4R)-4-phenyl-5,5′-dicyclohexyloxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-phenyl-5,5′-dimethoxyoxazoline]palladiumdichloride, 2,2′-methylenebis[(4R)-4-phenyl-5,5′-dimethoxyoxazoline]palladium dibromide,2,2′-methylenebis[(4R)-4-phenyl-5,5′-diethoxyoxazoline]palladiumdichloride,2,2′-methylenebis[(4R)-4-phenyl-5,5′-diethoxyoxazoline]palladiumdibromide, 2,2′-methylenebis[(4R)-4-phenyl-5,5′-diphenyloxazoline]palladium dichloride,2,2′-methylenebis[(4R)-4-phenyl-5,5′-diphenyloxazoline]palladiumdibromide,methylenebis[(4R)-4-methyl-5,5′-di-(2-methylphenyl)oxazoline]palladiumdibromide, methylenebis[(4R)-4-methyl-5,5′-di-(3-methylphenyl)oxazoline]palladium dibromide,methylenebis[(4R)-4-methyl-5,5′-di-(4-methylphenyl)oxazoline]palladiumdibromide, methylenebis[(4R)-4-methyl-5,5′-di-(2-methoxyphenyl)oxazoline]palladium dibromide,methylenebis[(4R)-4-methyl-5,5′-di-(3-methoxyphenyl)oxazoline]palladiumdibromide, methylenebis[(4R)-4-methyl-5,5′-di-(4-methoxyphenyl)oxazoline]palladium dibromide,methylenebis[spiro{(4R)-4-methyloxazoline-5,1′-cyclobutane}]palladiumdibromide,methylenebis[spiro{(4R)-4-methyloxazoline-5,1′-cyclopentane}]palladiumdibromide,methylenebis[spiro{(4R)-4-methyloxazoline-5,1′-cyclohexane}]palladiumdibromide,methylenebis[spiro{(4R)-4-methyloxazoline-5,1′-cycloheptane}]palladiumdibromide,2,2′-methylenebis[(4R)-4-isopropyl-5,5′-dimethyloxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-isopropyl-5,5′-diethyloxazoline]palladiumdibromide, 2,2′-methylenebis[(4R)-4-isopropyl-5,5′-di-n-propyloxazoline]palladium dibromide,methylenebis[(4R)-4-isopropyl-5,5′-diisopropyloxazoline]palladiumdibromide, 2,2′-methylenebis[(4R)-4-isopropyl-5,5′-dicyclohexyloxazoline]palladium dibromide,2,2′-methylenebis[(4R)-4-isopropyl-5,5′-diphenyloxazoline]palladiumdibromide, 2,2′-methylenebis[(4R)-4-isopropyl-5,5′-di-(2-methylphenyl)oxazoline]palladium dibromide,2,2′-methylenebis[(4R)-4-isopropyl-5,5′-di-(3-methylphenyl)oxazoline]palladiumdibromide, 2,2′-methylenebis[(4R)-4-isopropyl-5,5′-di-(4-methylphenyl)oxazoline]palladium dibromide,2,2′-methylenebis[(4R)-4-isopropyl-5,5′-di-(2-methoxyphenyl)oxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-isopropyl-5,5′-di-(3-methoxyphenyl)oxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-isopropyl-5,5′-di-(4-methoxyphenyl)oxazoline]palladiumdibromide, 2,2′-methylenebis[spiro{(4R)-4-isopropyloxazoline-5,1′-cyclobutane}]palladium dibromide,2,2′-methylenebis[spiro{(4R)-4-isopropyloxazoline-5,1′-cyclopentane}]palladiumdibromide,2,2′-methylenebis[spiro{(4R)-4-isopropyloxazoline-5,1′-cyclohexane}]palladiumdibromide, 2,2′-methylenebis[spiro{(4R)-4-isopropyloxazoline-5,1′-cycloheptane}]palladium dibromide,2,2′-methylenebis[(4R)-4-isobutyl-5,5′-dimethyloxazoline]palladiumdibromide, 2,2′-methylenebis[(4R)-4-isobutyl-5,5′-diethyloxazoline]palladium dibromide,2,2′-methylenebis[(4R)-4-isobutyl-5,5′-di-n-propyloxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-isobutyl-5,5′-diisopropyloxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-isobutyl-5,5′-dicyclohexyloxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-isobutyl-5,5′-diphenyloxazoline]palladiumdibromide, 2,2′-methylenebis[(4R)-4-isobutyl-5,5′-di-(2-methylphenyl)oxazoline]palladium dibromide,2,2′-methylenebis[(4R)-4-isobutyl-5,5′-di-(3-methylphenyl)oxazoline]palladiumdibromide, 2,2′-methylenebis[(4R)-4-isobutyl-5,5′-di-(4-methylphenyl)oxazoline]palladium dibromide,2,2′-methylenebis[(4R)-4-isobutyl-5,5′-di-(2-methoxyphenyl)oxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-isobutyl-5,5′-di-(3-methoxyphenyl)oxazoline]palladiumdibromide, 2,2′-methylenebis[(4R)-4-isobutyl-5,5′-di-(4-methoxyphenyl)oxazoline]palladium dibromide,2,2′-methylenebis[spiro{(4R)-4-isobutyloxazoline-5,1′-cyclobutane}]palladiumdibromide,2,2′-methylenebis[spiro{(4R)-4-isobutyloxazoline-5,1′-cyclopentane}]palladiumdibromide, 2,2′-methylenebis[spiro{(4R)-4-isobutyloxazoline-5,1′-cyclohexane}]palladium dibromide,2,2′-methylenebis[spiro{(4R)-4-isobutyloxazoline-5,1′-cycloheptane}]palladiumdibromide,2,2′-methylenebis[(4R)-4-tert-butyl-5,5′-dimethyloxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-tert-butyl-5,5′-diethyloxazoline]palladiumdibromide, 2,2′-methylenebis[(4R)-4-tert-butyl-5,5′-di-n-propyloxazoline]palladium dibromide,2,2′-methylenebis[(4R)-4-tert-butyl-5,5′-diisopropyloxazoline]palladiumdibromide, 2,2′-methylenebis[(4R)-4-tert-butyl-5,5′-diphenyloxazoline]palladium dibromide,2,2′-methylenebis[(4R)-4-tert-butyl-5,5′-dicyclohexyloxazoline]palladiumdibromide, 2,2′-methylenebis[(4R)-4-tert-butyl-5,5′-di-(2-methylphenyl)oxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-tert-butyl-5,5′-di-(3-methylphenyl)oxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-tert-butyl-5,5′-di-(4-methylphenyl)oxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-tert-butyl-5,5′-di-(2-methoxyphenyl)oxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-tert-butyl-5,5′-di-(3-methoxyphenyl)oxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-tert-butyl-5,5′-di-(4-methoxyphenyl)oxazoline]palladiumdibromide,2,2′-methylenebis[spiro{(4R)-4-tert-butyloxazoline-5,1′-cyclobutane}]palladiumdibromide,2,2′-methylenebis[spiro{(4R)-4-tert-butyloxazoline-5,1′-cyclopentane}]palladiumdibromide,2,2′-methylenebis[spiro{(4R)-4-tert-butyloxazoline-5,1′-cyclohexane}]palladiumdibromide,2,2′-methylenebis[spiro{(4R)-4-tert-butyloxazoline-5,1′-cycloheptane}]palladiumdibromide, 2,2′-methylenebis[(4R)-4-phenyl-5,5′-dimethyloxazoline]palladium dibromide,2,2′-methylenebis[(4R)-4-phenyl-5,5′-diethyloxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-phenyl-5,5′-di-n-propyloxazoline]palladiumdibromide, 2,2′-methylenebis[(4R)-4-phenyl-5,5′-diisopropyloxazoline]palladium dibromide,2,2′-methylenebis[(4R)-4-phenyl-5,5′-dicyclohexyloxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-phenyl-5,5′-diphenyloxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-phenyl-5,5′-di-(2-methylphenyl)oxazoline]palladiumdibromide, 2,2′-methylenebis[(4R)-4-phenyl-5,5′-di-(3-methylphenyl)oxazoline]palladium dibromide,2,2′-methylenebis[(4R)-4-phenyl-5,5′-di-(4-methylphenyl)oxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-phenyl-5,5′-di-(2-methoxyphenyl)oxazoline]palladiumdibromide, 2,2′-methylenebis[(4R)-4-phenyl-5,5′-di-(3-methoxyphenyl)oxazoline]palladium dibromide,2,2′-methylenebis[(4R)-4-phenyl-5,5′-di-(4-methoxyphenyl)oxazoline]palladiumdibromide,2,2′-methylenebis[spiro{(4R)-4-phenyloxazoline-5,1′-cyclobutane}]palladiumdibromide, 2,2′-methylenebis[spiro{(4R)-4-phenyloxazoline-5,1′-cyclopentane}]palladium dibromide,2,2′-methylenebis[spiro{(4R)-4-phenyloxazoline-5,1′-cyclohexane}]palladiumdibromide,2,2′-methylenebis[spiro{(4R)-4-phenyloxazoline-5,1′-cycloheptane}]palladiumdibromide,2,2′-methylenebis[(4R)-4-benzyl-5,5′-dimethyloxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-benzyl-5,5′-diethyloxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-benzyl-5,5′-di-n-propyloxazoline]palladiumdibromide, 2,2′-methylenebis[(4R)-4-benzyl-5,5′-diisopropyloxazoline]palladium dibromide,2,2′-methylenebis[(4R)-4-benzyl-5,5′-dicyclohexyloxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-benzyl-5,5′-diphenyloxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-benzyl-5,5′-di-(2-methylphenyl)oxazoline]palladiumdibromide, 2′-methylenebis[(4R)-4-benzyl-5,5′-di-(3-methylphenyl)oxazoline]palladium dibromide,2,2′-methylenebis[(4R)-4-benzyl-5,5′-di-(4-methylphenyl)oxazoline]palladiumdibromide,2,2′-methylenebis[(4R)-4-benzyl-5,5′-di-(2-methoxyphenyl)oxazoline]palladiumdibromide, 2,2′-methylenebis[(4R)-4-benzyl-5,5′-di-(3-methoxyphenyl)oxazoline]palladium dibromide,2,2′-methylenebis[(4R)-4-benzyl-5,5′-di-(4-methoxyphenyl)oxazoline]palladiumdibromide,2,2′-methylenebis[spiro{(4R)-4-benzyloxazoline-5,1′-cyclobutane}]palladiumdibromide,2,2′-methylenebis[spiro{(4R)-4-benzyloxazoline-5,1′-cyclopentane}]palladiumdibromide, 2,2′-methylenebis[spiro{(4R)-4-benzyloxazoline-5,1′-cyclohexane})]palladium dibromide,and2,2′-methylenebis[spiro{(4R)-4-benzyloxazoline-5,1′-cycloheptane}]palladiumdibromide; compounds obtained by replacing the term “(4R)” of theabove-exemplified compounds with the term “(4S)”; and antipodes anddiastreomers of the above-exemplified compounds.

Further examples of the transition metal compound represented by formula(4), wherein M¹ is a palladium atom, are[hydrotris(3,5-dimethylpyrazolyl)borate]palladium chloride,[hydrotris(3,5-dimethylpyrazolyl)borate]palladium bromide,[hydrotris(3,5-dimethylpyrazolyl)borate]palladium iodide,[hydrotris(3,5-dimethylpyrazolyl)borate]palladium methyl,[hydrotris(3,5-dimethylpyrazolyl)borate]palladium ethyl,[hydrotris(3,5-dimethylpyrazolyl)borate]palladium allyl,[hydrotris(3,5-dimethylpyrazolyl)borate]palladium methallyl,[hydrotris(3,5-diethylpyrazolyl)borate]palladium chloride,[hydrotris(3,5-diethylpyrazolyl)borate]palladium bromide,[hydrotris(3,5-diethylpyrazolyl)borate]palladium iodide,[hydrotris(3,5-diethylpyrazolyl)borate]palladium methyl,[hydrotris(3,5-diethylpyrazolyl)borate]palladium ethyl,[hydrotris(3,5-diethylpyrazolyl)borate]palladium allyl,[hydrotris(3,5-diethylpyrazolyl)borate]palladium methallyl,[hydrotris(3,5-di-tert-butylpyrazolyl)borate]palladium chloride,[hydrotris(3,5-di-tert-butylpyrazolyl)borate]palladium bromide,[hydrotris(3,5-di-tert-butylpyrazolyl)borate]palladium iodide,[hydrotris(3,5-di-tert-butylpyrazolyl)borate]palladium methyl,[hydrotris(3,5-di-tert-butylpyrazolyl)borate]palladium ethyl,[hydrotris(3,5-di-tert-butylpyrazolyl) borate]palladium allyl,[hydrotris(3,5-di-tert-butylpyrazolyl)borate]palladium methallyl,chloro(methyl) [N,N′-(ethane-1,2-diylidene)bis(aniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2-methylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2-ethylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2-n-propylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2-isopropylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2-n-butylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2-isobutylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2-n-hexylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(4-methylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2,6-dimethylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2,6-diethylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2,6-di-n-propylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2,6-diisopropylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2,6-di-n-butylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2,6-diisobutylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2,6-di-n-hexylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2-methyl-6-ethylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2-methyl-6-n-propylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2-methyl-6-isopropylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2-methyl-6-butylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2-ethyl-6-n-propylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2-ethyl-6-isopropylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2-ethyl-6-n-butylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2-n-propyl-6-isopropylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2-n-propyl-6-n-butylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2-isopropyl-6-n-butylaniline-1N)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2,4,6-trimethylaniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis{2,4-dimethyl-6-(2-methylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis{2,4-dimethyl-6-(2-ethylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis{2,4-dimethyl-6-(2-n-propylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis{2,4-dimethyl-6-(2-isopropylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis{2,4-dimethyl-6-(2,6-dimethylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis(2,4-dimethyl-6-(2,6-diethylphenyl)aniline-κN)]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis{2,4-dimethyl-6-(2,6-di-n-propylphenyl)aniline-κN)}]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis{2,4-dimethyl-6-(2,6-diisopropylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis{2,4-dimethyl-6-(2-methyl-6-ethylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis{2,4-dimethyl-6-(2-methyl-6-n-propylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis{2,4-dimethyl-6-(2-methyl-6-isopropylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis{2,4-dimethyl-6-(2-ethyl-6-n-propylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis{-2,4-dimethyl-6-(2-ethyl-6-isopropylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(ethane-1,2-diylidene)bis{2,4-dimethyl-6-(1-naphthyl)anilineK N}]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(aniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2-methylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2-ethylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2-n-propylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2-isopropylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2-n-butylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2-isobutylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2-n-hexylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(4-methylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2,6-dimethylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2,6-diethylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2,6-di-n-propylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2,6-diisopropylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2,6-di-n-butylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2,6-diisobutylamine-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2,6-di-n-hexylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2-methyl-6-ethylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2-methyl-6-n-propylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2-methyl-6-isopropylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2-methyl-6-butylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2-ethyl-6-n-propylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2-ethyl-6-isopropylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2-ethyl-6-n-butylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2-n-propyl-6-isopropylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2-n-propyl-6-n-butylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2-isopropyl-6-n-butylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis(2,4,6-trimethylaniline-κN)]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis{2,4-dimethyl-6-(2-methylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis{2,4-dimethyl-6-(2-ethylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis{2,4-dimethyl-6-(2-n-propylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis{2,4-dimethyl-6-(2-isopropylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis{2,4-dimethyl-6-(2,6-dimethylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis{2,4-dimethyl-6-(2,6-diethylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis{2,4-dimethyl-6-(2,6-di-n-propylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis{2,4-dimethyl-6-(2,6-diisopropylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis{2,4-dimethyl-6-(2-methyl-6-ethylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis{2,4-dimethyl-6-(2-methyl-6-n-propylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis{2,4-dimethyl-6-(2-methyl-6-isopropylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis{2,4-dimethyl-6-(2-ethyl-6-n-propylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis{2,4-dimethyl-6-(2-ethyl-6-isopropylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(butane-2,3-diylidene)bis{2,4-dimethyl-6-(1-naphthyl)aniline-κN)}]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(aniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2-methylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2-ethylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2-n-propylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2-isopropylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2-n-butylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2-isobutylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2-n-hexylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(4-methylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2,6-dimethylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2,6-diethylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2,6-di-n-propylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2,6-diisopropylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2,6-di-n-butylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2,6-diisobutylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2,6-di-n-hexylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2,6-dichloroaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2-methyl-6-ethylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2-methyl-6-n-propylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2-methyl-6-isopropylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2-methyl-6-butylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2-ethyl-6-n-propylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2-ethyl-6-isopropylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2-ethyl-6-n-butylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2-n-propyl-6-isopropylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2-n-propyl-6-n-butylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2-isopropyl-6-n-butylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis(2,4,6-trimethylaniline-κN)]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis{2,4-dimethyl-6-(2-methylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis{2,4-dimethyl-6-(2-ethylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis{2,4-dimethyl-6-(2-n-propylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis{2,4-dimethyl-6-(2-isopropylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis{2,4-dimethyl-6-(2,6-dimethylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis{2,4-dimethyl-6-(2,6-diethylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis{2,4-dimethyl-6-(2,6-di-n-propylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis{2,4-dimethyl-6-(2,6-diisopropylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis{2,4-dimethyl-6-(2-methyl-6-ethylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis{2,4-dimethyl-6-(2-methyl-6-n-propylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis{2,4-dimethyl-6-(2-methyl-6-isopropylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis{2,4-dimethyl-6-(2-ethyl-6-n-propylphenyl)aniline-κN}]palladium,chloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis{2,4-dimethyl-6-(2-ethyl-6-isopropylphenyl)aniline-κN}]palladium, andchloro(methyl)[N,N′-(1,2-dihydroacenaphthylene-1,2-diylidene)bis{2,4-dimethyl-6-(1-naphthyl)aniline-κN}]palladium.

Examples of the transition metal compound represented by formula (4),wherein M¹ is a nickel atom, a cobalt atom, a rhodium atom or aruthenium atom, are compounds obtained by replacing the term “palladium”of the above-exemplified palladium compounds with the term “nickel”,“cobalt”, “rhodium” or “ruthenium”.

Examples of the transition metal compound represented by formula (4),wherein M is an iron atom, are2,6-bis-[1-(2,6-dimethylphenylimino)ethyl]pyridineiron dichloride,2,6-bis-[1-(2,6-diisopropylphenylimino)ethyl]pyridineiron dichloride,2,6-bis-[1-(2,6-dichlorophenylimino) ethyl]pyridineiron dichloride,2,6-bis-[1-(2-methyl-6-isopropylphenylimino)ethyl]pyridineirondichloride, 2,6-bis-[1-(2-tert-butylphenylimino)ethyl]pyridineirondichloride, [hydrotris(3,5-dimethylpyrazolyl)borate]iron chloride,[hydrotris(3,5-dimethylpyrazolyl)borate]iron bromide,[hydrotris(3,5-dimethylpyrazolyl)borate]iron iodide,[hydrotris(3,5-dimethylpyrazolyl)borate]iron methyl,[hydrotris(3,5-dimethylpyrazolyl)borate]iron ethyl,[hydrotris(3,5-dimethylpyrazolyl)borate]iron allyl,[hydrotris(3,5-dimethylpyrazolyl)borate]iron methallyl,[hydrotris(3,5-diethylpyrazolyl)borate]iron chloride,[hydrotris(3,5-diethylpyrazolyl)borate]iron bromide,[hydrotris(3,5-diethylpyrazolyl)borate]iron iodide,[hydrotris(3,5-diethylpyrazolyl)borate]iron methyl,[hydrotris(3,5-diethylpyrazolyl)borate]iron ethyl,[hydrotris(3,5-diethylpyrazolyl)borate]iron allyl,[hydrotris(3,5-diethylpyrazolyl)borate]iron methallyl,[hydrotris(3,5-di-tert-butylpyrazolyl)borate]iron chloride,[hydrotris(3,5-di-tert-butylpyrazolyl)borate]iron bromide,[hydrotris(3,5-di-tert-butylpyrazolyl)borate]iron iodide,[hydrotris(3,5-di-tert-butylpyrazolyl)borate]iron methyl,[hydrotris(3,5-di-tert-butylpyrazolyl)borate]iron ethyl,[hydrotris(3,5-di-tert-butylpyrazolyl)borate]iron allyl, and[hydrotris(3,5-di-tert-butylpyrazolyl)borate]iron methallyl.

Examples of the transition metal compound represented by the formula(4), wherein M¹ is a cobalt atom or a nickel atom, are compoundsobtained by replacing the term “iron” of the above-exemplified ironcompounds with the term “cobalt” or “nickel”.

The above-mentioned transition metal compounds may be used incombination of two or more thereof.

The transition metal compound is preferably a compound represented bythe following formula [I]:

wherein M² is a transition metal atom of Group 10 of the Periodic Tableof the elements; R³ and R⁴ are independently of each other a hydrogenatom, a halogen atom, an alkyl group, an aralkyl group, an aryl group, asilyl group, a siloxy group, an alkoxy group, an aralkyloxy group or anaryloxy group; R⁵ and R⁶ are independently of each other a hydrocarbylgroup having 1 to 30 carbon atoms; and R⁷ and R⁸ are independently ofeach other a hydrogen atom or a hydrocarbyl group having 1 to 20 carbonatoms, and R⁷ and R⁸ may be linked with each other to form a ring.

M² is preferably a nickel atom or a palladium atom, and furtherpreferably a palladium atom.

Examples of the halogen atom of R³ and R⁴ are a fluorine atom, achlorine atom, a bromine atom, and an iodine atom. Among them, preferredis a chlorine atom or a bromine atom.

Examples of the alkyl group of R³ and R⁴ are linear alkyl groups such asa methyl group, an ethyl group, and a n-butyl group; branched alkylgroups such as an isopropyl group, an isobutyl group, a tert-butylgroup, and a neopentyl group; and cyclic alkyl groups such as acyclohexyl group and a cyclooctyl group. Among them, preferred is alinear alkyl group, more preferred is a linear alkyl group having 1 to12 carbon atoms, and further preferred is a methyl group.

Examples of the aralky group of R³ and R⁴ are a benzyl group and aphenethyl group. Among them, preferred is a benzyl group.

Examples of the aryl group of R³ and R⁴ are a phenyl group, a naphthylgroup, a 4-tolyl group, a mesityl group, and a biphenyl group. Amongthem, preferred is a phenyl group, a 4-tolyl group or a mesityl group.

Examples of the silyl group of R³ and R⁴ are monosubstituted silyl groupsuch as a methylsilyl group, an ethylsilyl group, and a phenylsilylgroup; disubstituted silyl groups such as a dimethylsilyl group, adiethylsilyl group, and a diphenylsilyl group; and trisubstituted silylgroups such as a trimethylsilyl group, a trimethoxysilyl group, adimethylmethoxysilyl group, a methyldimethoxysilyl group, atriethylsilyl group, a triethoxysilyl group, a tri-n-propylsilyl group,a triisopropylsilyl group, a tri-n-butylsilyl group, atri-sec-butylsilyl group, a tert-butyldimethylsilyl group, atriisobutylsilyl group, a tert-butyldiphenylsilyl group, acyclohexyldimethylsilyl group, a tricyclohexylsilyl group, and atriphenylsilyl group. Among them, preferred are trisubstituted silylgroups, and more preferred is a trimethylsilyl group, a triethylsilylgroup, a triphenylsilyl group, a tert-butyldimethylsilyl group, atert-butyldiphenylsilyl group, a cyclohexyldimethylsilyl group, or atriisopropylsilyl group.

Examples of the siloxy group of R³ and R⁴ are a trimethylsiloxy group, atrimethoxysiloxy group, a dimethylmethoxysiloxy group, amethyldimethoxysiloxy group, a triethylsiloxy group, a triethoxysiloxygroup, a tri-n-propylsiloxy group, a triisopropylsiloxy group, atri-n-butylsiloxy group, a tri-sec-butylsiloxy group, atert-butyldimethylsiloxy group, a triisobutylsiloxy group, atert-butyldiphenylsiloxy group, a cyclohexyldimethylsiloxy group, atricyclohexylsiloxy group, and a triphenylsiloxy group. Among them,preferred is a trimethylsiloxy group, a triethylsiloxy group, atriphenylsiloxy group, a tert-butyldimethylsiloxy group, atert-butyldiphenylsiloxy group, a cyclohexyldimethylsiloxy group,

Examples of the alkoxy group of R³ and R⁴ are a methoxy group, an ethoxygroup, a n-propoxy group, an isopropoxy group, a n-butoxy group, asec-butoxy group, a tert-butoxy group, a n-pentyloxy group, aneopentyloxy group, a n-hexyloxy group, a n-octyloxy group, an-dodecyloxy group, a n-pentadecyloxy group, and a n-eicosyloxy group.Among them, preferred is an alkoxy group having 1 to 20 carbon atoms,and more preferred is a methoxy group, an ethoxy group, an isopropoxygroup, or a tert-butoxy group.

Examples of the aralkyloxy group of R³ and R⁴ are a benzyloxy group, a(2-methylphenyl)methoxy group, a (3-methylphenyl)methoxy group, a(4-methylphenyl)methoxy group, a (2,3-dimethylphenyl)methoxy group, a(2,4-dimethylphenyl)methoxy group, a (2,5-dimethylphenyl)methoxy group,a (2,6-dimethylphenyl)methoxy group, a (3,4-dimethylphenyl)methoxygroup, a (3,5-dimethylphenyl)methoxy group, a(2,3,4-trimethylphenyl)methoxy group, a (2,3,5-trimethylphenyl)methoxygroup, a (2,3,6-trimethylphenyl)methoxy group, a(2,4,5-trimethylphenyl)methoxy group, a (2,4,6-trimethylphenyl)methoxygroup, a (3,4,5-trimethylphenyl)methoxy group, a(2,3,4,5-tetramethylphenyl)methoxy group, a(2,3,4,6-tetramethylphenyl)methoxy group, a(2,3,5,6-tetramethylphenyl)methoxy group, a (pentamethylphenyl)methoxygroup, an (ethylphenyl)methoxy group, a (n-propylphenyl)methoxy group,an (isopropylphenyl)methoxy group, a (n-butylphenyl)methoxy group, a(sec-butylphenyl)methoxy group, a (tert-butylphenyl)methoxy group, a(n-hexylphenyl)methoxy group, a (n-octylphenyl)methoxy group, a(n-decylphenyl)methoxy group, a naphthylmethoxy group, and ananthrathenylmethoxy group. Among them, preferred is a benzyloxy group.

Examples of the aryloxy group of R³ and R⁴ are a phenoxy group, a2-methylphenoxy group, a 3-methylphenoxy group, a 4-methylphenoxy group,a 2,3-dimethylphenoxy group, a 2,4-dimethylphenoxy group, a2,5-dimethylphenoxy group, a 2,6-dimethylphenoxy group, a3,4-dimethylphenoxy group, a 3,5-dimethylphenoxy group, a2-tert-butyl-3-methylphenoxy group, a 2-tert-butyl-4-methylphenoxygroup, a 2-tert-butyl-5-methylphenoxy group, a2-tert-butyl-6-methylphenoxy group, a 2,3,4-trimethylphenoxy group, a2,3,5-trimethylphenoxy group, a 2,3,6-trimethylphenoxy group, a2,4,5-trimethylphenoxy group, a 2,4,6-trimethylphenoxy group, a2-tert-butyl-3,4-dimethylphenoxy group, a2-tert-butyl-3,5-dimethylphenoxy group, a2-tert-butyl-3,6-dimethylphenoxy group, a2,6-di-tert-butyl-3-methylphenoxy group, a2-tert-butyl-4,5-dimethylphenoxy group, a2,6-di-tert-butyl-4-methylphenoxy group, a 3,4,5-trimethylphenoxy group,a 2,3,4,5-tetramethylphenoxy group, a2-tert-butyl-3,4,5-trimethylphenoxy group, a 2,3,4,6-tetramethylphenoxygroup, a 2-tert-butyl-3,4,6-trimethylphenoxy group, a2,6-di-tert-butyl-3,4-dimethylphenoxy group, a2,3,5,6-tetramethylphenoxy group, a 2-tert-butyl-3,5,6-trimethylphenoxygroup, a 2,6-di-tert-butyl-3,5-dimethylphenoxy group, apentamethylphenoxy group, an ethylphenoxy group, a n-propylphenoxygroup, an isopropylphenoxy group, a n-butylphenoxy group, asec-butylphenoxy group, a tert-butylphenoxy group, a n-hexylphenoxygroup, a n-octylphenoxy group, a n-decylphenoxy group, a naphthoxygroup, and an anthrathenoxy group. Among them, preferred is an aryloxygroup having 6 to 20 carbon atoms.

R³ and R⁴ are preferably a hydrogen atom, a halogen atom, an alkyl groupor an aryl group; more preferably a hydrogen atom, a halogen atom or anon-substituted linear alkyl group having 1 to 12 carbon atoms; andparticularly preferred is a chlorine atom or a methyl group.

Examples of the hydrocarbyl group having 1 to 30 carbon atoms of R⁵ andR⁶ are an alkyl group, an aralkyl group and an aryl group. Those groupsmay have a substituent such as a halogen atom, a hydrocarbyloxy group, anitro group, a sulfonyl group, and a silyl group.

Examples of the alkyl group of R⁵ and R⁶ are linear alkyl groups such asa methyl group, an ethyl group, and a n-butyl group; branched alkylgroups such as an isopropyl group, an isobutyl group, a tert-butylgroup, and a neopentyl group; and cyclic alkyl groups such as acyclohexyl group and a cyclooctyl group. Among them, preferred is abranched alkyl group, more preferred is a branched alkyl group having 1to 12 carbon atoms, and further preferred is an isopropyl group or atert-butyl group.

Examples of the aralkyl group of R⁵ and R⁶ are a benzyl group and aphenethyl group. Among them, preferred is a benzyl group.

Examples of the aryl group of R⁵ and R⁶ are a phenyl group, a2-methylphenyl group, a 2-ethylphenyl group, a 2-n-propylphenyl group, a2-isopropylphenyl group, a 2-n-butylphenyl group, a 2-isobutylphenylgroup, a 2-n-hexylphenyl group, a 4-methylphenyl group, a2,6-dimethylphenyl group, a 2,6-diethylphenyl group, a2,6-di-n-propylphenyl group, a 2,6-diisopropylphenyl group, a2,6-di-n-butylphenyl group, a 2,6-diisobutylphenyl group, a2,6-di-n-hexylphenyl group, a 2-methyl-6-ethylphenyl group, a2-methyl-6-n-propylphenyl group, a 2-methyl-6-isopropylphenyl group, a2-methyl-6-butylphenyl group, a 2-ethyl-6-n-propylphenyl group, a2-ethyl-6-isopropylphenyl group, a 2-ethyl-6-n-butylphenyl group, a2-n-propyl-6-isopropylphenyl group, a 2-n-propyl-6-n-butylphenyl group,a 2-isopropyl-6-n-butylphenyl group, a 2,4,6-trimethylphenyl group, a2,4-dimethyl-6-(2-methylphenyl)phenyl group, a2,4-dimethyl-6-(2-ethylphenyl)phenyl group, a2,4-dimethyl-6-(2-n-propylphenyl)phenyl group, a2,4-dimethyl-6-(2-isopropylphenyl)phenyl group, a2,4-dimethyl-6-(2,6-dimethylphenyl)phenyl group, a2,4-dimethyl-6-(2,6-diethylphenyl)phenyl group, a2,4-dimethyl-6-(2,6-di-n-propylphenyl)phenyl group, a2,4-dimethyl-6-(2,6-diisopropylphenyl)phenyl group, a2,4-dimethyl-6-(2-methyl-6-ethylphenyl)phenyl group, a2,4-dimethyl-6-(2-methyl-6-n-propylphenyl)phenyl group, a2,4-dimethyl-6-(2-methyl-6-isopropylphenyl)phenyl group, a2,4-dimethyl-6-(2-ethyl-6-n-propylphenyl)phenyl group, a2,4-dimethyl-6-(2-ethyl-6-isopropylphenyl)phenyl group, and a2,4-dimethyl-6-(1-naphthyl)phenyl group. Among them, preferred is anaryl group having 6 to 30 carbon atoms, and more preferred is an arylgroup having 7 to 30 carbon atoms.

Examples of the hydrocarbyl group having 1 to 20 carbon atoms of R⁷ andR⁸ are an alkyl group and an aryl group. Those groups may have asubstituent such as a halogen atom, a hydrocarbyloxy group, a nitrogroup, a sulfonyl group, and a silyl group.

Examples of the alkyl group of R⁷ and R⁸ are linear alkyl groups such asa methyl group, an ethyl group, and a n-butyl group; branched alkylgroups such as an isopropyl group, an isobutyl group, a tert-butylgroup, and a neopentyl group; and cyclic alkyl groups such as acyclohexyl group and a cyclooctyl group. Among them, preferred is alinear alkyl group, more preferred is a linear alkyl group having 1 to12 carbon atoms, and further preferred is a methyl group or an ethylgroup.

Examples of the aryl group of R⁷ and R⁸ are a phenyl group, a naphthylgroup, a 4-tolyl group, and a mesityl group. Among them, preferred is anaryl group having 6 to 20 carbon atoms, more preferred is an aryl grouphaving 6 to 12 carbon atoms, and further preferred is a phenyl group ora mesityl group.

When R⁷ and R⁸ are linked with each other to form a ring, examples ofthe ring are an aliphatic ring and an aromatic ring. Those rings mayhave a substituent. Examples of a divalent group forming the aliphaticring are a 1,2-ethylene group, a 1,2-cyclohexylene group, a1,2-norbornene group, a 2,3-butene group, a 2,3-dimethyl-2,3-butenegroup, and a 2,4-pentene group. Examples of a divalent group forming thearomatic ring are a 1,2-phenylene group and a naphthalen-1,8-diyl group.Among them, preferred is a naphthalen-1,8-diyl group. One bond containedin each of these divalent groups is linked with the R⁷-carrying carbonatom in formula [I], and the other bond contained therein is linked withthe R⁸-carrying carbon atom therein.

A transition metal compound used in the present invention is preferablya compound represented by the following formula [II] encompassed by theformula [I], from a viewpoint of production of a polymer containing morethan 25% by mol of diisotactic triad, and preferably threodiisotactictriad:

wherein M², R³, R⁴, R⁷ and R⁸ are the same as those defined in the aboveformula [I]; R⁹ and R¹⁰ are independently of each other a hydrogen atom,a halogen atom, an alkyl group, an aralkyl group, a silyl group, asiloxy group, an alkoxy group, an aralkyloxy group, an amino group, anamide group, an imide group, or a hydrocarbylthio group; R¹¹ and R¹² areindependently of each other an aryl group having 7 to 20; and R¹³ andR¹⁴ are independently of each other a hydrogen atom, a halogen atom, analkyl group, an aralkyl group, an aryl group, a silyl group, a siloxygroup, an alkoxy group, an aralkyloxy group, an aryloxy group, an aminogroup, an amide group, an imide group, or a hydrocarbylthio group.

R⁹ and R¹⁰ are preferably an alkyl group, further preferably an alkylgroup having 1 to 12 carbon atoms, and particularly preferably a methylgroup, an ethyl group, a n-propyl group, an isopropyl group, a n-butylgroup, an isobutyl group, or a tert-butyl group.

Examples of R¹¹ and R¹² are a 2-methylphenyl group, a 3-methylphenylgroup, a 4-methylphenyl group, a 2,3-dimethylphenyl group, a2,4-dimethylphenyl group, a 2,5-dimethylphenyl group, a2,6-dimethylphenyl group, a 3,4-dimethylphenyl group, a3,5-dimethylphenyl group, a 3,6-dimethylphenyl group, a naphthyl group,a 2-methyl-1-naphthyl group, a 3-methyl-1-naphthyl group, a4-methyl-1-naphthyl group, a 2,3-dimethyl-1-naphthyl group, a2,4-dimethyl-1-naphthyl group, a 2,5-dimethyl-1-naphthyl group, a2,6-dimethyl-1-naphthyl group, a 3,4-dimethyl-1-naphthyl group, a3,5-dimethyl-1-naphthyl group, a 3,6-dimethyl-1-naphthyl group, ananthracenyl group, a 2-methyl-1-anthracenyl group, a3-methyl-10-anthracenyl group, a 4-methyl-10-anthracenyl group, a2,3-dimethyl-10-anthracenyl group, a 2,4-dimethyl-10-anthracenyl group,a 2,5-dimethyl-10-anthracenyl group, a 2,6-dimethyl-10-anthracenylgroup, a 3,4-dimethyl-10-anthracenyl group, a3,5-dimethyl-10-anthracenyl group, a 3,6-dimethyl-10-anthracenyl group,and 2-methyl-10-anthracenyl group. Among them, preferred is asubstituent-having phenyl group, a naphthyl group or an anthracenylgroup, and further preferred is a 2-methylphenyl group or a naphthylgroup.

R¹³ and R¹⁴ are preferably a hydrogen atom or an alkyl group, morepreferably a hydrogen atom or an alkyl group having 1 to 12 carbonatoms, and further preferably a methyl group, an ethyl group, a n-propylgroup, an isopropyl group, a n-butyl group, or an isobutyl group.

Also, a transition metal compound used in the present invention ispreferably a compound represented by the following formula [III]encompassed by the formula [I], from a viewpoint of production of apolymer containing more than 25% by mol of disyndiotactic triad, andpreferably threodisyndiotactic triad:

wherein M², R³, R⁴, R⁷ and R⁸ are the same as those defined in the aboveformula [I]; R¹⁵, R¹⁶, R¹⁷ and R¹⁸ are independently of one another ahydrogen atom, a halogen atom, an alkyl group, an aralkyl group, an arylgroup, a silyl group, a siloxy group, an alkoxy group, an aralkyloxygroup, an aryloxy group, an amino group, an amide group, an imide group,or a hydrocarbylthio group; and R¹⁹ and R²⁰ are independently of eachother a hydrogen atom, a halogen atom, an alkyl group, an aralkyl group,an aryl group, a silyl group, a siloxy group, an alkoxy group, anaralkyloxy group, an aryloxy group, an amino group, an amide group, animide group, or a hydrocarbylthio group.

R¹⁵, R¹⁶, R¹⁷ and R¹⁸ are preferably a hydrogen atom, an alkyl group oran aryl group, more preferably a hydrogen atom, an alkyl group having 1to 12 carbon atoms, or an aryl group having 6 to 20 carbon atoms, andfurther preferably a hydrogen atom, a methyl group, an ethyl group, an-propyl group, an isopropyl group, a n-butyl group, an isobutyl group,a tert-butyl group, or a phenyl group.

R¹⁹ and R²⁰ are preferably a hydrogen atom, an alkyl group or an arylgroup, more preferably a hydrogen atom, an alkyl group having 1 to 12carbon atoms, or an aryl group having 6 to 20 carbon atoms, and furtherpreferably a hydrogen atom, a methyl group, an ethyl group, a n-propylgroup, an isopropyl group, a n-butyl group, an isobutyl group, atert-butyl group, or a phenyl group.

Compounds represented by the following formula [IV] are also preferableas a transition metal compound used in the present invention:

wherein M³ is a transition metal atom of Group 8 to 11 of the PeriodicTable of the elements; R³ and R⁴ are the same as those defined in theabove formula [I]; and R²¹ to R²⁷ are independently of one another ahydrogen atom, a halogen atom, an alkyl group, an aralkyl group, an arylgroup, a silyl group, a siloxy group, an alkoxy group, an aralkyloxygroup, an aryloxy group, an amino group, an amide group, an imide group,or a hydrocarbylthio group, and any two or more of R²¹ to R²⁷ may belinked with one another to form a ring.

M³ is preferably an iron atom, a ruthenium atom, a cobalt atom, arhodium atom, a nickel atom, a palladium atom, or a copper atom, andfurther preferably an iron atom or a cobalt atom.

Examples of the halogen atom of R²¹ to R²⁷ are a fluorine atom, achlorine atom, a bromine atom, and an iodine atom. Among them, preferredis a chlorine atom or a bromine atom.

Examples of the alkyl group of R²¹ to R²⁷ are linear alkyl groups suchas a methyl group, an ethyl group, a n-propyl group, a n-butyl group,and a n-pentyl group; branched alkyl groups such as an isopropyl group,an isobutyl group, a tert-butyl group, and a neopentyl group; and cyclicalkyl groups such as a cyclopropyl group, a cyclobutyl group, acyclopentyl group, a cyclohexyl group and a cyclooctyl group. Amongthem, preferred is a branched alkyl group, more preferred is a branchedalkyl group having 1 to 12 carbon atoms, and further preferred is anisopropyl group or a tert-butyl group.

Examples of the aralkyl group of R²¹ to R²⁷ are a benzyl group and aphenethyl group. Among them, preferred is a benzyl group.

Examples of the aryl group of R²¹ to R²⁷ are a phenyl group, a2-methylphenyl group, a 2-ethylphenyl group, a 2-n-propylphenyl group, a2-isopropylphenyl group, a 2-n-butylphenyl group, a 2-isobutylphenylgroup, a 2-tert-butylphenyl group, a 2-n-hexylphenyl group, a2-cyclohexylphenyl group, a 3-methylphenyl group, a 3-ethylphenyl group,a 3-n-propylphenyl group, a 3-isopropylphenyl group, a 3-n-butylphenylgroup, a 3-isobutylphenyl group, a 3-tert-butylphenyl group, a3-n-hexylphenyl group, a 3-cyclohexylphenyl group, a 4-methylphenylgroup, a 4-ethylphenyl group, a 4-n-propylphenyl group, a4-isopropylphenyl group, a 4-n-butylphenyl group, a 4-isobutylphenylgroup, a 4-tert-butylphenyl group, a 4-n-hexylphenyl group, a4-cyclohexylphenyl group, a 2,6-dimethylphenyl group, a2,6-diethylphenyl group, a 2,6-di-n-propylphenyl group, a2,6-diisopropylphenyl group, a 2,6-di-n-butylphenyl group, a2,6-diisobutylphenyl group, a 2,6-di-tert-butylphenyl group, a2,6-di-n-hexylphenyl group, a 2,6-dicyclohexylphenyl group, a2-methyl-6-ethylphenyl group, a 2-methyl-6-n-propylphenyl group, a2-methyl-6-isopropylphenyl group, a 2-methyl-6-n-butylphenyl group, a2-methyl-6-isobutylphenyl group, a 2-methyl-6-tert-butylphenyl group, a2-methyl-6-n-hexylphenyl group, a 2-methyl-6-cyclohexylphenyl group, a2-ethyl-6-n-propylphenyl group, a 2-ethyl-6-isopropylphenyl group, a2-ethyl-6-n-butylphenyl group, a 2-ethyl-6-isobutylphenyl group, a2-ethyl-6-tert-butylphenyl group, a 2-ethyl-6-n-hexylphenyl group, a2-ethyl-6-cyclohexylphenyl group, a 2-n-propyl-6-isopropylphenyl group,a 2-n-propyl-6-n-butylphenyl group, a 2-n-propyl-6-isobutylphenyl group,a 2-n-propyl-6-tert-butylphenyl group, a 2-n-propyl-6-n-hexylphenylgroup, a 2-n-propyl-6-cyclohexylphenyl group, a2-isopropyl-6-n-butylphenyl group, a 2-isopropyl-6-isobutylphenyl group,a 2-isopropyl-6-tert-butylphenyl group, a 2-isopropyl-6-n-hexylphenylgroup, a 2-isopropyl-6-cyclohexylphenyl group, a2-n-butyl-6-isobutylphenyl group, a 2-n-butyl-6-tert-butylphenyl group,a 2-n-butyl-6-n-hexylphenyl group, a 2-n-butyl-6-cyclohexylphenyl group,a 2-isobutyl-6-tert-butylphenyl group, a 2-isobutyl-6-n-hexylphenylgroup, a 2-isobutyl-6-cyclohexylphenyl group, a2-tert-butyl-6-n-hexylphenyl group, a 2-tert-butyl-6-cyclohexylphenylgroup, a 2-n-hexyl-6-cyclohexylphenyl group, a 2,4-diisopropylphenylgroup, a 2,4-di-n-butylphenyl group, a 2,4-diisobutylphenyl group, a2,4-di-tert-butylphenyl group, a 2,4-di-n-hexylphenyl group, a2,4-dicyclohexylphenyl group, a 2-ethyl-4-methylphenyl group, a2-n-propyl-4-methylphenyl group, a 2-isopropyl-4-methylphenyl group, a2-n-butyl-4-methylphenyl group, a 2-isobutyl-4-methylphenyl group, a2-tert-butyl-4-methylphenyl group, a 2-n-hexyl-4-methylphenyl group, a2-cyclohexyl-4-methylphenyl group, a 2-n-propyl-4-ethylphenyl group, a2-isopropyl-4-ethylphenyl group, a 2-n-butyl-4-ethylphenyl group, a2-isobutyl-4-ethylphenyl group, a 2-tert-butyl-4-ethylphenyl group, a2-n-hexyl-4-ethylphenyl group, a 2-cyclohexyl-4-ethylphenyl group, a2-isopropyl-4-n-propylphenyl group, a 2-n-butyl-4-n-propylphenyl group,a 2-isobutyl-4-n-propylphenyl group, a 2-tert-butyl-4-n-propylphenylgroup, a 2-n-hexyl-4-n-propylphenyl group, a2-cyclohexyl-4-n-propylphenyl group, a 2-n-butyl-4-isopropylphenylgroup, a 2-isobutyl-4-isopropylphenyl group, a2-tert-butyl-4-isopropylphenyl group, a 2-n-hexyl-4-isopropylphenylgroup, a 2-cyclohexyl-4-isopropylphenyl group, a2-isobutyl-4-n-butylphenyl group, a 2-tert-butyl-4-n-butylphenyl group,a 2-n-hexyl-4-n-butylphenyl group, a 2-cyclohexyl-4-n-butylphenyl group,a 2-tert-butyl-4-isobutylphenyl group, a 2-n-hexyl-4-isobutylphenylgroup, a 2-cyclohexyl-4-isobutylphenyl group, a2-n-hexyl-4-tert-butylphenyl group, a 2-cyclohexyl-4-tert-butylphenylgroup, a 2-cyclohexyl-4-n-hexylphenyl group, a 2,5-dimethylphenyl group,a 2,5-diethylphenyl group, a 2,5-di-n-propylphenyl group, a2,5-diisopropylphenyl group, a 2,5-di-n-butylphenyl group, a2,5-diisobutylphenyl group, a 2,5-di-tert-butylphenyl group, a2,5-di-n-hexylphenyl group, a 2,5-dicyclohexylphenyl group, a2,4,6-trimethylphenyl group, a 2,4,6-triethylphenyl group, a2,4,6-tri-n-propylphenyl group, a 2,4,6-triisopropylphenyl group, a2,4,6-tri-n-butylphenyl group, a 2,4,6-triisobutylphenyl group, a2,4,6-tri-tert-butylphenyl group, a 2,4,6-tri-n-hexylphenyl group, a2,4,6-tricyclohexylphenyl group, a 2,6-diethyl-4-methylphenyl group, a2,6-di-n-propyl-4-methylphenyl group, a 2,6-diisopropyl-4-methylphenylgroup, a 2,6-di-n-butyl-4-methylphenyl group, a2,6-diisobutyl-4-methylphenyl group, a 2,6-di-tert-butyl-4-methylphenylgroup, a 2,6-di-n-hexyl-4-methylphenyl group, a2,6-dicyclohexyl-4-methylphenyl group, a2,4-dimethyl-6-(2-methylphenyl)phenyl group, a2,4-dimethyl-6-(2-ethylphenyl)phenyl group, a2,4-dimethyl-6-(2-n-propylphenyl)phenyl group, a2,4-dimethyl-6-(2-isopropylphenyl)phenyl group, a2,4-dimethyl-6-(2,6-dimethylphenyl)phenyl group, a2,4-dimethyl-6-(2,6-diethylphenyl)phenyl group, a2,4-dimethyl-6-(2,6-di-n-propylphenyl)phenyl group, a2,4-dimethyl-6-(2,6-diisopropylphenyl)phenyl group, a2,4-dimethyl-6-(2-methyl-6-ethylphenyl)phenyl group, a2,4-dimethyl-6-(2-methyl-6-n-propylphenyl)phenyl group, a2,4-dimethyl-6-(2-methyl-6-isopropylphenyl)phenyl group, a2,4-dimethyl-6-(2-ethyl-6-n-propylphenyl)phenyl group, a2,4-dimethyl-6-(2-ethyl-6-isopropylphenyl)phenyl group, and a2,4-dimethyl-6-(1-naphthyl)phenyl group.

Examples of the silyl group of R²¹ to R²⁷ are mono-substituted silylgroups such as a methylsilyl group, an ethylsilyl group, and aphenylsilyl group; di-substituted silyl groups such as a dimethylsilylgroup, a diethylsilyl group, and a diphenylsilyl group; andtri-substituted silyl groups such as a trimethylsilyl group, atrimethoxysilyl group, a dimethylmethoxysilyl group, amethyldimethoxysilyl group, a triethylsilyl group, a triethoxysilylgroup, a tri-n-propylsilyl group, a triisopropylsilyl group, atri-n-butylsilyl group, a tri-sec-butylsilyl group, atert-butyldimethylsilyl group, a triisobutylsilyl group, atert-butyldiphenylsilyl group, a cyclohexyldimethylsilyl group, atricyclohexylsilyl group, and a triphenylsilyl group. Among them,preferred are tri-substituted silyl groups, and further preferred is atrimethylsilyl group, a triethylsilyl group, a triphenylsilyl group, atert-butyldimethylsilyl group, a tert-butyldiphenylsilyl group, acyclohexyldimethylsilyl group, or a triisopropylsilyl group.

Examples of the siloxy group of R²¹ to R²⁷ are a trimethylsiloxy group,a trimethoxysiloxy group, a dimethylmethoxysiloxy group, amethyldimethoxysiloxy group, a triethylsiloxy group, a triethoxysiloxygroup, a tri-n-propylsiloxy group, a triisopropylsiloxy group, atri-n-butylsiloxy group, a tri-sec-butylsiloxy group, atert-butyldimethylsiloxy group, a triisobutylsiloxy group, atert-butyldiphenylsiloxy group, a cyclohexydimethylsiloxy group, atricyclohexylsiloxy group, and a triphenylsiloxy group. Among them,preferred is a trialkylsiloxy group, and further preferred is atrimethylsiloxy group, a triethylsiloxy group, and a triphenylsiloxygroup, a tert-butyldimethylsiloxy group, a tert-butyldiphenylsiloxygroup, a cyclohexyldimethylsiloxy group, or a triisopropylsiloxy group.

Examples of the alkoxy group of R²¹ to R²⁷ are a methoxy group, anethoxy group, a n-propoxy group, an isopropoxy group, a n-butoxy group,a sec-butoxy group, a tert-butoxy group, a n-pentyloxy group, aneopentyloxy group, a n-hexyloxy group, a n-octyloxy group, an-dodecyloxy group, a n-pentadecyloxy group, and a n-eicosyloxy group.Among them, preferred is a methoxy group, an ethoxy group, an isopropoxygroup, or a tert-butoxy group.

Examples of the aralkyloxy group of R²¹ to R²⁷ are a benzyloxy group, a(2-methylphenyl)methoxy group, a (3-methylphenyl)methoxy group, a(4-methylphenyl)methoxy group, a (2,3-dimethylphenyl)methoxy group, a(2,4-dimethylphenyl)methoxy group, a (2,5-dimethylphenyl)methoxy group,a (2,6-dimethylphenyl)methoxy group, a (3,4-dimethylphenyl)methoxygroup, a (3,5-dimethylphenyl)methoxy group, a(2,3,4-trimethylphenyl)methoxy group, a (2,3,5-trimethylphenyl)methoxygroup, a (2,3,6-trimethylphenyl)methoxy group, a(2,4,5-trimethylphenyl)methoxy group, a (2,4,6-trimethylphenyl)methoxygroup, a (3,4,5-trimethylphenyl)methoxy group, a(2,3,4,5-tetramethylphenyl)methoxy group, a(2,3,4,6-tetramethylphenyl)methoxy group, a(2,3,5,6-tetramethylphenyl)methoxy group, a (pentamethylphenyl)methoxygroup, an (ethylphenyl)methoxy group, a (n-propylphenyl)methoxy group,an (isopropylphenyl)methoxy group, a (n-butylphenyl)methoxy group, a(sec-butylphenyl)methoxy group, a (tert-butylphenyl)methoxy group, a(n-hexylphenyl)methoxy group, a (n-octylphenyl)methoxy group, a(n-decylphenyl)methoxy group, a naphthylmethoxy group, and ananthrathenylmethoxy group. Among them, preferred is a benzyloxy group.

Examples of the aryloxy group of R²¹ to R²⁷ are a phenoxy group, a2-methylphenoxy group, a 3-methylphenoxy group, a 4-methylphenoxy group,a 2,3-dimethylphenoxy group, a 2,4-dimethylphenoxy group, a2,5-dimethylphenoxy group, a 2,6-dimethylphenoxy group, a3,4-dimethylphenoxy group, a 3,5-dimethylphenoxy group, a2-tert-butyl-3-methylphenoxy group, a 2-tert-butyl-4-methylphenoxygroup, a 2-tert-butyl-5-methylphenoxy group, a2-tert-butyl-6-methylphenoxy group, a 2,3,4-trimethylphenoxy group, a2,3,5-trimethylphenoxy group, a 2,3,6-trimethylphenoxy group, a2,4,5-trimethylphenoxy group, a 2,4,6-trimethylphenoxy group, a2-tert-butyl-3,4-dimethylphenoxy group, a2-tert-butyl-3,5-dimethylphenoxy group, a2-tert-butyl-3,6-dimethylphenoxy group, a2,6-di-tert-butyl-3-methylphenoxy group, a2-tert-butyl-4,5-dimethylphenoxy group, a2,6-di-tert-butyl-4-methylphenoxy group, a 3,4,5-trimethylphenoxy group,a 2,3,4,5-tetramethylphenoxy group, a2-tert-butyl-3,4,5-trimethylphenoxy group, a 2,3,4,6-tetramethylphenoxygroup, a 2-tert-butyl-3,4,6-trimethylphenoxy group, a2,6-di-tert-butyl-3,4-dimethylphenoxy group, a2,3,5,6-tetramethylphenoxy group, a 2-tert-butyl-3,5,6-trimethylphenoxygroup, a 2,6-di-tert-butyl-3,5-dimethylphenoxy group, apentamethylphenoxy group, an ethylphenoxy group, a n-propylphenoxygroup, an isopropylphenoxy group, a n-butylphenoxy group, asec-butylphenoxy group, a tert-butylphenoxy group, a n-hexylphenoxygroup, a n-octylphenoxy group, a n-decylphenoxy group, a naphthoxygroup, and an anthrathenoxy group.

Examples of the amino group of R²¹ to R²⁷ are linear alkylamino groupssuch as an N-methylamino group, an N-ethylamino group, an N-n-butylaminogroup, an N,N-dimethylamino group, an N,N-diethylamino group, and anN,N-di-n-butylamino group; branched alkylamino groups such as anN,N-diisopropylamino group, an N,N-diisobutylamino group, anN,N-di-tert-butylamino group, and an N,N-dineopentylamino group; andcyclic alkylamino groups such as an N,N-dicyclohexylamino group and anN,N-dicyclooctylamino group.

Examples of the amide group of R²¹ to R²⁷ are an ethanamide group, anN-n-butylethanamide group, an N-methylethanamide group, anN-ethylethanamide group, an N-n-butylhexanamide group, an isopropanamidegroup, an isobutanamide group, a tert-butanamide group, a neopentanamidegroup, a cyclohexanamide group, and a cyclooctanamide group.

Examples of the imide group of R²¹ to R²⁷ are a succinimide group, amaleimide group, and a phthalimide group.

Examples of the hydrocarbylthio group of R²¹ to R²⁷ are alkylthio groupssuch as a methylthio group, an ethylthio group, an isopropylthio group,and a tert-butylthio group; arylthio groups such as a phenylthio groupand a naphthylthio group; and aralkylthio groups such as a benzylthiogroup and a 9-fluorenylmethylthio group.

R²¹ to R²⁷ may have one or more substituents such as a halogen atom, analkoxy group, an aryloxy group, an aralkyloxy group, a nitro group, anamino group, an amide group, an imide group, a silyl group, a siloxygroup, a sulfonyl group, and a hydrocarbylthio group.

When any two or more of R²¹ to R²⁷ are linked with one another to form aring, examples of the ring are an aliphatic ring and an aromatic ring.Those rings may have one or more substituents such as a halogen atom, analkoxy group, an aryloxy group, an aralkyloxy group, a nitro group, anamino group, an amide group, an imide group, a silyl group, a siloxygroup, a sulfonyl group, and a hydrocarbylthio group.

When any two of R²¹ to R²⁷ are linked with each other to form analiphatic ring, examples of a divalent group forming the aliphatic ringare a methylene group, an ethane-1,2-diyl group, a propane-1,3-diylgroup, a propane-1,2-diyl group, a butane-1,2-diyl group, abutane-1,3-diyl group, a butane-1,4-diyl group, a pentane-1,2-diylgroup, a pentane-1,3-diyl group, a pentane-1,4-diyl group, apentane-1,5-diyl group, an ethylene-1,2-diyl group, acyclohexane-1,2-diyl group, a cyclohexane-1,3-diyl group, anorbornane-1,2-diyl group, a norbornane-1-ene-1,2-diyl group, abutane-1-ene-1,2-diyl group, a butane-1-ene-1,3-diyl group, abutane-1-ene-2,3-diyl group, a butane-2-ene-1,2-diyl group, abutane-2-ene-1,3-diyl group, a butane-2-ene-2,3-diyl group, abutane-1,3-diene-1,2-diyl group, a butane-1,3-diene-1,3-diyl group, abutane-1,3-diene-1,4-diyl group, a dimethyl-2,3-butene-2,3-diyl group,and a pentene-2,4-diyl group.

When any two of R²¹ to R²⁷ are linked with each other to form anaromatic ring, examples of a divalent group forming the aromatic ringare a benzen-1,2-diyl group, a 3-methylbenzen-1,2-diyl group, a4-methylbenzen-1,2-diyl group, a 3-ethylbenzen-1,2-diyl group, a4-ethylbenzen-1,2-diyl group, a 3-n-propylbenzen-1,2-diyl group, a4-n-propylbenzen-1,2-diyl group, a 3-n-butylbenzen-1,2-diyl group, a4-n-butylbenzen-1,2-diyl group, a 3-isopropylbenzen-1,2-diyl group, a4-isopropylbenzen-1,2-diyl group, a 3-isobutylbenzen-1,2-diyl group, a4-isobutylbenzen-1,2-diyl group, a 3-tert-butylbenzen-1,2-diyl group, a4-tert-butylbenzen-1,2-diyl group, a benzen-1,3-diyl group, a2-methylbenzen-1,3-diyl group, a 4-methylbenzen-1,3-diyl group, abiphenyl-2,2′-diyl group, a benzene-1,2-dimethylene group,abenzene-1,3-dimethylene group, and a naphthalen-1,8-diyl group.

One bond contained in each of the above-mentioned divalent groups islinked with a carbon atom carrying one of R²¹ to R²⁷, and the other bondcontained therein is linked with a carbon atom carrying another of R²¹to R²⁷,

An organoaluminum compound in the present invention may be a compoundknown in the art. Examples of the organoaluminum compound are thefollowing compounds (1) to (3), and a combination of two or morethereof:

-   -   (1) an organoaluminum compound represented by the formula, E¹        _(d)AlX² _(3-d);

(2) a cyclic alumoxane represented by the formula, {—Al(E²)-O—}_(e); and

(3) a linear alumoxane represented by the formula,E³{—Al(E³)-O—}_(f)AlE³ ₂,

wherein E¹, E² and E³ are independently of one another a hydrocarbylgroup, and when plural E¹s, E²s or E³s exist, they are the same as, ordifferent from one another; X² is a hydrogen atom or a halogen atom, andwhen plural Xs exist, they are the same as, or different from oneanother; d is a number satisfying 0<d≦₃; e is an integer of 2 or more,and preferably an integer of 2 to 40; and f is an integer of 1 or more,and preferably an integer of 1 to 40.

The hydrocarbyl group of E¹, E² and E³ is preferably a hydrocarbyl grouphaving 1 to 8 carbon atoms, and more preferably an alkyl group having 1to 8 carbon atoms. Examples of the alkyl group of E¹, E² and E³ are amethyl group, an ethyl group, a n-propyl group, an isopropyl group, an-butyl group, an isobutyl group, a n-pentyl group, and a neopentylgroup. Among them, preferred is a methyl group or an isobutyl group.

Examples of the above-mentioned organoaluminum compound (1) aretrialkylaluminums such as trimethylaluminum, triethylaluminum,tripropylaluminum, triisobutylaluminum, and trihexylaluminum;dialkylaluminum chlorides such as dimethylaluminum chloride,diethylaluminum chloride, dipropylaluminum chloride, diisobutylaluminumchloride and dihexylaluminum chloride; alkylaluminum dichlorides such asmethylaluminum dichloride, ethylaluminum dichloride, propylaluminumdichloride, isobutylaluminum dichloride and hexylaluminum dichloride;and dialkylaluminum hydrides such as dimethylaluminum hydride,diethylaluminum hydride, dipropylaluminum hydride, diisobutylaluminumhydride and dihexylaluminum hydride. Among them, preferred is atrialkylaluminum, and more preferred is triethylaluminum ortriisobutylaluminum.

The above-mentioned cyclic alumoxane (2) and linear alumoxane (3) can beproduced according to various processes. Those processes are notparticularly limited, and may be those known in the art. Examples of theprocess are (i) a process comprising the step of contacting a solutionof a trialkylaluminum such as trimethylaluminum in a suitable organicsolvent such as benzene and an aliphatic hydrocarbon with water, and(ii) a process comprising the step of contacting a trialkylaluminum suchas trimethylaluminum with a crystal water-containing metal salt such ascopper sulfate hydrate.

A boron compound in the present invention may be a compound known in theart. Examples of the boron compound are the following compounds (1) to(3), and a combination of two or more thereof:

-   -   (1) a boron compound represented by the formula, BQ¹Q²Q³;    -   (2) a boron compound represented by the formula, G⁺(BQ¹Q²Q³Q⁴)⁻;        and    -   (3) a boron compound represented by the formula,        (J-H)⁺(BQ¹Q²Q³Q⁴)⁻;        wherein B is a trivalent boron atom; Q¹, Q², Q³ and Q⁴ are        independently of one another a halogen atom, a hydrocarbyl        group, a halogenated hydrocarbyl group, a silyl group, a siloxy        group, an alkoxy group, an amino group, an amido group, or an        imido group; G⁺ is an inorganic or organic cation; J is a        neutral Lewis base; and (J-H)⁺ is a Broensted acid.

Q¹, Q², Q³ and Q⁴ in the above-mentioned formulas are preferably ahalogen atom, a hydrocarbyl group having 1 to 20 carbon atoms, ahalogenated hydrocarbyl group having 1 to 20 carbon atoms, a silyl grouphaving 1 to 20 carbon atoms, a siloxy group having 1 to 20 carbon atoms,a C₂₋₂₀ hydrocarbyl group-carrying amino group, a C₂₋₂₀ hydrocarbylgroup-carrying amido group, or a C₂₋₂₀ hydrocarbyl group-carrying imidogroup; more preferably a halogen atom, a hydrocarbyl group having 1 to20 carbon atoms, or a halogenated hydrocarbyl group having 1 to 20carbon atoms; further preferably a C₁₋₂₀ fluorinated hydrocarbyl groupcontaining one or more fluorine atoms; and particularly preferably aC₆₋₂₀ fluorinated aryl group containing one or more fluorine atoms.

Examples of the above-mentioned boron compound (1) aretris(pentafluorophenyl)borane, tris(2,3,5,6-tetrafluorophenyl)borane,tris(2,3,4,5-tetrafluorophenyl)borane,tris(3,4,5-trifluorophenyl)borane, tris(2,3,4-trifluorophenyl)borane,and phenylbis(pentafluorophenyl)borane. Among them, most preferred istris(pentafluorophenyl)borane.

Examples of an inorganic cation, G⁺, in the above-mentioned boroncompound (2) are a ferrocenium cation, an alkyl group-having ferroceniumcation, and a silver cation. An example of an organic cation, G⁺,therein is a barbenium cation such as a triphenylmethyl cation. Amongthem, G⁺ is preferably a carbenium cation, and particularly preferably atriphenylmethyl cation.

Examples of (BQ¹Q²Q³Q⁴)⁻ in the above-mentioned boron compound (2) aretetrakis(pentafluorophenyl)borate,tetrakis(2,3,5,6-tetrafluorophenyl)borate,tetrakis(2,3,4,5-tetrafluorophenyl)borate,tetrakis(3,4,5-trifluorophenyl)borate,tetrakis(2,3,4-trifluorophenyl)borate,phenyltris(pentafluorophenyl)borate, andtetrakis(3,5-bistrifluoromethylphenyl)borate.

Examples of the above-mentioned boron compound (2) are lithiumtetrakis(3,5-bistrifluoromethylphenyl)borate, sodiumtetrakis(3,5-bistrifluoromethylphenyl)borate, potassiumtetrakis(3,5-bistrifluoromethylphenyl)borate, silvertetrakis(pentafluorophenyl)borate, ferroceniumtetrakis(pentafluorophenyl)borate, 1,1′-dimethylferroceniumtetrakis(pentafluorophenyl)borate, tetrabutylphosphponiumtetrakis(pentafluorophenyl)borate, tetraphenylphosphponiumtetrakis(pentafluorophenyl)borate, tetramethylammoniumtetrakis(pentafluorophenyl)borate, trimethylsulphonuimtetrakis(pentafluorophenyl)borate, diphenyliodoniumtetrakis(pentafluorophenyl)borate, triphenylcarbeniumtetrakis(pentafluorophenyl)borate, and triphenylcarbeniumtetrakis(3,5-bistrifluoromethylphenyl)borate. Among them, most preferredis triphenylcarbenium tetrakis(pentafluorophenyl)borate.

Examples of (J-H)⁺ in the above-mentioned boron compound (3) are atrialkylammonium, an N,N-dialkylanilinium, a dialkylammonium, and atriarylphosphonium. Examples of the (BQ¹Q²Q³Q⁴)⁻ therein are the same asthose mentioned above.

Examples of the above-mentioned boron compound (3) are triethylammoniumtetrakis(pentafluorophenyl)borate, tripropylammoniumtetrakis(pentafluorophenyl)borate, tri(n-butyl)ammoniumtetrakis(pentafluorophenyl)borate, tri(n-butyl)ammoniumtetrakis(3,5-bistrifluoromethylphenyl) borate, N,N-dimethylaniliniumtetrakis(pentafluorophenyl) borate, N,N-diethylaniliniumtetrakis(pentafluorophenyl) borate,N,N-dimethyl-2,4,6-trimethylanilinium tetrakis(pentafluorophenyl)borate, N,N-dimethylanilinium tetrakis(3,5-bistrifluoromethylphenyl)borate, diisopropylammoniumtetrakis(pentafluorophenyl)borate, dicyclohexylammoniumtetrakis(pentafluorophenyl)borate, triphenylphosphoniumtetrakis(pentafluorophenyl)borate, tri(methylphenyl) phosphoniumtetrakis(pentafluorophenyl)borate, and tri(dimethylphenyl)phosphoniumtetrakis(pentafluorophenyl) borate. Among them, most preferred istri(n-butyl)ammonium tetrakis(pentafluorophenyl)borate, orN,N-dimethylanilinium tetrakis(pentafluorophenyl)borate.

The boron compound is preferably the above-mentioned boron compound (2)or (3), and particularly preferably triphenylcarbeniumtetrakis(pentafluorophenyl)borate, tri(n-butyl)ammoniumtetrakis(pentafluorophenyl)borate, or N,N-dimethylaniliniumtetrakis(pentafluorophenyl)borate.

A molecular weight of the polymer of the present invention is notparticularly limited. Its weight-average molecular weight (Mw) ispreferably 1,000 to 10,000,000, more preferably 2,000 to 5,000,000, andmost preferably 4,000 to 3,000,000.

A molecular weight distribution of the polymer of the present inventionis not particularly limited. It is preferably 1.0 to 100, morepreferably 1.0 to 50, and most preferably 1.0 to 20.

A glass-transition temperature or a melting point of the polymer of thepresent invention is preferably −20° C. or higher, more preferably 20°C. or higher, and most preferably 50° C. or higher.

In the present invention, a method for contacting (i) theabove-mentioned transition metal compound, (ii) the above-mentionedorganoaluminum compound and/or boron compound, (iii) the compoundrepresented by the formula (3), and (iv) the above-mentioned olefin,with one another, is not particularly limited.

When forming a polymerization catalyst by contacting the transitionmetal compound with the organoaluminum compound, the organoaluminumcompound is preferably the above-mentioned cyclic alumoxane, linearalumoxane, or a combination thereof, in order to form a highactivity-having polymerization catalyst. When forming a polymerizationcatalyst by contacting the transition metal compound, the organoaluminumcompound and the boron compound with one another, the organoaluminumcompound is preferably the organoaluminum compound represented by theabove-mentioned first formula, E¹ _(d)AlZ_(3-d), in order to form a highactivity-having polymerization catalyst.

The organoaluminum compound is used in amount of generally 0.1 to 10,000parts by mol, and preferably 5 to 2,000 parts by mol, per one mol of thetransition metal compound. The amount of smaller than 0.1 part by molmay result in an insufficient activity of a polymerization catalyst. Theamount of larger than 10,000 parts by mol may result in production of atoo low molecular weight-having polymer, because of, for example, chaintransfer to the organoaluminum compound, or may result in a too lowactivity-having polymerization catalyst. The boron compound is used inamount of generally 0.01 to 100 parts by mol, and preferably 0.5 to 10parts by mol, per one mol of the transition metal compound. The amountof smaller than 0.01 part by mol may result in an insufficient activityof a polymerization catalyst. The amount of larger than 100 parts by molis not preferable from an economical point of view.

Each of the transition metal compound, the organoaluminum compound, andthe boron compound may be used as a solution thereof. Examples of asolvent for the solution are methylene chloride, chloroform, toluene,pentane, hexane, and heptane. Among them, preferred is methylenechloride, chloroform, or toluene.

A solution of the transition metal compound has a concentration ofgenerally 0.01 to 500 μmol/L, preferably 0.05 to 100 μmol/L, and morepreferably 0.05 to 50 μmol/L. A solution of the organoaluminum compoundhas a concentration of generally 0.01 to 10,000 μmol/L, preferably 0.1to 5,000 μmol/L, and more preferably 0.1 to 2,000 μmol/L, in terms of anamount of an aluminum atom contained in the solution. A solution of theboron compound has a concentration of generally 0.01 to 500 μmol/L,preferably 0.05 to 200 μmol/L, and more preferably 0.05 to 100 μmol/L.When the solution of the transition metal compound has a concentrationof lower than 0.01 μmol/L, when the solution of the organoaluminumcompound has a concentration of lower than 0.01 μmol/L in terms of anamount of an aluminum atom contained in the solution, or when thesolution of the boron compound has a concentration of lower than 0.01μmol/L, a large amount of a solvent is necessary to prepare thesolution, which is not preferable from an economical point of view. Whenthe solution of the transition metal compound has a concentration ofhigher than 500 μmol/L, when the solution of the organoaluminum compoundhas a concentration of higher than 10,000 μmol/L in terms of an amountof an aluminum atom contained in the solution, or when the solution ofthe boron compound has a concentration of higher than 500 μmol/L, thetransition metal compound, the organoaluminum compound, or the boroncompound may not be sufficiently dissolved in a solvent, and therefore,the compound may be deposited in the solution.

A polymerization catalyst in the present invention may be combined witha carrier or a support comprising particles of inorganic or organiccompounds. Examples of the inorganic compounds are silica gel andalumina, and an example of the organic compounds is a styreneunit-containing polymer.

A polymerization method is not particularly limited in the presentinvention. Examples thereof are a gas-phase polymerization method, abulk polymerization method, a solution polymerization method using asuitable polymerization solvent, and a suspension polymerization methodusing the same, which are a batch-wise polymerization method or acontinuous polymerization method. The polymerization solvent is asolvent non-deactivating a polymerization catalyst. Examples of thesolvent are a hydrocarbon solvent such as benzene, toluene, pentane,hexane, heptane, and cyclohexane; and a halogenated solvent such asdichloromethane and chloroform.

A polymerization temperature is not particularly limited in the presentinvention, and generally −100 to 250° C., and preferably −50 to 200° C.The polymerization temperature of lower than −100° C. may result in aninsufficient activity of a polymerization catalyst. The polymerizationtemperature of higher than 250° C. may result in production of a too lowmolecular weight-having polymer, or may result in no production of apolymer containing the unit represented by the formula (1), due tooccurrence of a side reaction such as an isomerization reaction.

In order to regulate a molecular weight of a polymer produced, a chaintransfer agent such as hydrogen may be used.

A polymerization time is not particularly limited in the presentinvention, and generally one minute to 72 hours. The polymerization timeof shorter than one minute may result in an insufficient yield of apolymer produced. The polymerization time of longer than 72 hours isdisadvantageous from an economical point of view.

The polymer of the present invention may be used in combination withvarious additives such as weatherability stabilizers, lubricants,pigments, dyes, antistatic agents, antioxidants, antifogging agents,rust-inhibiting agents, surfactants, and electroconductive agents. Thepolymer of the present invention may also be used in combination with apolymer known in the art such as a low-density polyethylene, ahigh-density polyethylene, a linear low-density polyethylene, anethylene-acrylic acid ester copolymer, an ethylene-methacrylic acidester copolymer, an ethylene-vinyl acetate copolymer, anethylene-α-olefin copolymer elastomer, and polypropylene.

The polymer of the present invention can be molded according to anextrusion molding method or an injection molding method. Those methodsmay be known in the art. Examples of the extrusion molding method are(1) an inflation molding method comprising the steps of (1-1) extrudinga molten resin through a circular die, thereby forming an extrudedproduct, (1-2) blowing the extruded product into a cylindrical film orsheet, and (1-3) rewinding the film or sheet, (2) a T-die molding methodcomprising the steps of (2-1) extruding a molten resin through a lineardie, thereby forming a film or sheet, and (2-2) rewinding the film orsheet, and (3) a calender molding method.

EXAMPLE

The present invention is explained with reference to the followingExamples, which do not limit the scope of the present invention.

Reference Example 1 Preparation of4-(tert-butyldimethylsiloxy)-1,6-heptadiene represented by the formula(3)

There were supplied 6.5 g of imidazole manufactured by Wako PureChemical Industries, Ltd. to a 100 mL-two neck flask, and thereto, 50 mLof anhydrous N,N-dimethylformaide manufactured by Wako Pure ChemicalIndustries, Ltd., and 5.78 mL of 1,6-heptadien-4-ol manufactured byAldrich Chemical Company were added. The obtained mixture was cooleddown to 0° C. To the mixture, 6.5 g of tert-butyldimethylsilyl chloridemanufactured by Tokyo Chemical Industry Co., Ltd. were added, and theresultant mixture was stirred for 12 hours at a room temperature. Then,an excess amount of water was added thereto, thereby terminating thereaction. A product contained in the reaction mixture was extracted withhexane, and the obtained organic extract was dried over anhydrous sodiumsulfate manufactured by Nacalai Tesque, Inc. The dried hexane solutionwas distilled in vacuo, thereby obtaining 2.88 g (yield: 30%) of4-(tert-butyldimethylsiloxy)-1,6-heptadiene as clear colorless oil.

Reference Example 2 Preparation of 4-(triisopropylsiloxy)-1,6-heptadienerepresented by the formula (3)

There was supplied 1.35 g of imidazole manufactured by Wako PureChemical Industries, Ltd. to a 50 mL-Schlenk tube, and thereto, 10 mL ofanhydrous N,N-dimethylformaide manufactured by Wako Pure ChemicalIndustries, Ltd., and 1.2 mL of 1,6-heptadien-4-ol manufactured byAldrich Chemical Company were added. The obtained mixture was cooleddown to 0° C. To the mixture, 1.93 mL of triisopropylsilyl chloridemanufactured by Tokyo Chemical Industry Co., Ltd. was added, and theresultant mixture was stirred for 85 hours at a room temperature. Then,an excess amount of water was added thereto, thereby terminating thereaction. A product contained in the reaction mixture was extracted withhexane, and the obtained organic extract was dried over anhydrous sodiumsulfate manufactured by Nacalai Tesque, Inc. The dried hexane solutionwas distilled in vacuo, thereby obtaining 1.1 g (yield: 46%) of4-(triisopropylsiloxy)-1,6-heptadiene at 93° C. under 21 mmHg as clearcolorless oil.

Reference Example 3 Preparation of2,6-bis[1-(2-methyl-6-isopropylphenylimino) ethyl]pyridineirondichloride Transition Metal Compound

The captioned iron complex used in the following Example was prepared asfollows, according to a method disclosed in Journal of The AmericanChemical Society, Vol. 121, pages 8728-8740 (1999), authored by GeorgeJ. P. Britovsek, Michael Bruce, Vernon C. Gibson, Brian S. Kimberley,Peter J. Maddox, Sergio Mastroianni, Stuart J. McTavish, Carl Redshaw,Gregory A. Solan, Staffan Stroemberg, Andrew J. P. White, and David J.Williams. Other complexes used in the following Example were alsoprepared according to that method.

(1) Preparation of 2,6-bis[1-(2-methyl-6-isopropylphenylimino)ethyl]pyridine

There were supplied 325 mg of 2,6-diacetylpyridine manufactured byAldrich Chemical Company to a 25 mL-Schlenk tube. Thereto, 5 mL ofanhydrous ethanol manufactured by Kanto Chemical Co., Inc., 0.62 mL of2-methyl-6-isopropylaniline manufactured by Tokyo Chemical Industry Co.,Ltd., and a few drops of acetic acid manufactured by Kanto Chemical Co.,Inc. were added. The obtained mixture was refluxed for 24 hours. Then,the solvent contained in the mixture was distilled off, and theresultant mixture was subjected to recrystallization with methanol,thereby obtaining 298 mg (yield: 35%) of2,6-bis[1-(2-methyl-6-isopropylphenylimino)ethyl]pyridine as a yellowpowder.

(2) Preparation of 2,6-bis[1-(2-methyl-6-isopropylphenylimino)ethyl]pyridineiron dichloride

There were supplied 100 mg of2,6-bis[1-(2-methyl-6-isopropylphenylimino)ethyl]pyridine prepared inthe above (1) to a 25 mL-Schlenk tube. Thereto, 2.5 mL ofstabilizer-free anhydrous tetrahydrofuran manufactured by KantoChemical, and 30 mg of iron chloride (II) anhydride (having a form of abead) manufactured by Aldrich Chemical Company were added. Then, theresultant mixture was subjected to reaction for 2 hours at a roomtemperature. The solvent contained in the reaction mixture was distilledoff, and the resultant solid was washed with diethyl ether and then withhexane, thereby obtaining 104 mg of2,6-bis[1-(2-methyl-6-isopropylphenylimino)ethyl]pyridineiron dichlorideas a blue powder.

Example 1

There were put 7.3 mg of 2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridinecobalt dichloride (transition metal compound)in a 25 mL-Schlenk tube. Thereto, 1.2 mL of a toluene solution ofmodified methylalminoxane (MMAO: organoaluminum compound), the toluenesolution having an aluminum concentration of 6.6% by weight, and a tradename of MMAO-3A manufactured by Tosoh-finechem, and 0.16 mL of1,6-heptadiene (compound represented by the formula (3)) manufactured byTokyo Chemical Industry Co., Ltd., in this order. The resultant mixturewas subjected to polymerization reaction for 5 hours at a roomtemperature. The reaction mixture was poured into an excess amount of amixed solution of hydrochloric acid with methanol, and a precipitatedwhite powder was washed with methanol, thereby obtaining 102 mg of ahomopolymer (white powder) of 1,6-heptadiene having units represented bythe formula (1).

The homopolymer was hardly soluble in tetrahydrofuran at a roomtemperature, and was soluble in chloroform at a room temperature. Thehomopolymer had a number-average molecular weight (Mn) of 10,000; 100%of a trans-form in view of its relative configuration between A⁷ and A⁸;no stereoregularity; and a glass-transition temperature of 3.2° C. in arange between −100° C. and 250° C. Results are shown in Table 1.

The above-mentioned number-average molecular weight (Mn) and proportionof the trans-form were measured according to a ¹³C-NMR method using anequipment, LA-500, manufactured by JEOL LTD, under the followingconditions; and the above-mentioned existence of the unit represented bythe formula (1) was confirmed by assigning signals in the range of 23 to50 ppm of a ¹³C-NMR spectrum obtained by the ¹³C-NMR method to a linearhydrocarbyl structure and a 5-membered hydrocarbyl structure containedin the unit represented by the formula (1):

-   -   measurement solvent of chloroform-d₁;    -   measurement temperature of room temperature;    -   sample concentration of 50 mg-sample/0.5 mL-solution; and    -   reference material of chloroform-d₁ (77 ppm).

The above-mentioned stereoregularity was measured using an equipment,LA-500, manufactured by JEOL LTD according to a ¹³C-NMR methodcomprising the steps of:

(1) preparing a solution of a polymer in chloroform-d₁ having aconcentration of preferably 286 mg/mL;

(2) measuring a ¹³C-NMR spectrum of the solution;

(3) obtaining a peak area (A₁) existing in a range of 46.2 to 46.6 ppmin the spectrum, and a peak area (A₂) existing in a range of 46.9 to47.3 ppm therein, respectively, provided that a peak assigned tochloroform-d₁ appears at 77 ppm; and

(4) calculating the stereoregularity based on the following formulas,threodiisotactic triad (%)=100A ₁/(A ₁ +A ₂)threodisyndiotactic triad (%)=100A ₂/(A ₁ +A ₂).

The above-mentioned glass-transition temperature was measured accordingto a differential scanning calorimetry (DSC) using an equipment,SSC-5200, manufactured by Seiko Instruments & Electronics Ltd. under thefollowing conditions:

-   -   heating from 25° C. to 135° C. at a rate of 10° C./minute, and        keeping at 135° C. for 5 minutes; then,    -   cooling from 135° C. to −60° C. at a rate of 20° C./minute, and        keeping at −60° C. for 5 minutes; and then,    -   measuring under heating from −60° C. to 150° C. at a rate of 10°        C./minute.

Example 2

Example 1 was repeated except that 0.16 mL of 1,6-heptadiene was changedto 322 mg of 4-(triisopropylsiloxy)-1,6-heptadiene, thereby obtainingquantitatively a homopolymer (white powder) of4-(triisopropylsiloxy)-1,6-heptadiene having units represented by theformula (1).

The homopolymer was insoluble in chloroform or tetrahydrofuran at a roomtemperature, and was soluble in 1,1,2,2-tetrachloroethane at 130° C. Thehomopolymer had a trans-form in amount of 100% in view of its relativeconfiguration between A⁷ and A⁸, and had no stereoregularity. Resultsare shown in Table 1.

Example 3

There were put 7.3 mg of2,6-bis[1-(2,6-diisopropylphenylimino)ethyl}pyridineiron dichloride(transition metal compound) in a 25 mL-Schlenk tube. Thereto, 0.92 mL ofpurified toluene, 0.28 mL of a toluene solution of MMAO (organoaluminumcompound), the toluene solution having an aluminum concentration of 6.6%by weight, and a trade name of MMAO-3A manufactured by Tosoh-finechem,and 0.16 mL of 1,6-heptadiene (compound represented by the formula (3))manufactured by Tokyo Chemical Industry Co., Ltd., in this order. Theresultant mixture was subjected to polymerization reaction for 5 hoursat a room temperature. The reaction mixture was poured into an excessamount of a mixed solution of hydrochloric acid with methanol, and aprecipitated white powder was washed with methanol, thereby obtaining 72mg of a homopolymer (white powder) of 1,6-heptadiene having unitsrepresented by the formula (1).

The homopolymer was insoluble in chloroform or tetrahydrofuran at a roomtemperature, and was soluble in 1,1,2,2-tetrachloroethane at 130° C. Thehomopolymer had a number-average molecular weight (Mn) of 3,000; 70% ofa cis-form in view of its relative configuration between A⁷ and A⁸; and37% of erythrodiisotactic triad. Results are shown in Table 2.

Example 4

Example 3 was repeated except that the transition metal compound waschanged to 6.0 mg of2,6-bis[1-(2,6-dimethylphenylimino)ethyl}pyridineiron dichloride,thereby obtaining 90 mg of a homopolymer (white powder) of1,6-heptadiene having units represented by the formula (1).

The homopolymer was insoluble in chloroform or tetrahydrofuran at a roomtemperature, and was soluble in 1,1,2,2-tetrachloroethane at 130° C. Thehomopolymer had a number-average molecular weight (Mn) of 6,000; 95% ofa cis-form in view of its relative configuration between A⁷ and A⁸; andno stereoregularity. Results are shown in Table 2.

Example 5

Example 3 was repeated except that the transition metal compound waschanged to 6.9 mg ofdichloro[2,6-bis{1-(2,6-dichlorophenylimino)ethyl}pyridine-κN]iron,thereby obtaining 112 mg of a homopolymer (white powder) of1,6-heptadiene having units represented by the formula (1).

The homopolymer was insoluble in chloroform or tetrahydrofuran at a roomtemperature, and was soluble in 1,1,2,2-tetrachloroethane at 130° C. Thehomopolymer had a number-average molecular weight (Mn) of 14,000; 95% ofa cis-form in view of its relative configuration between A⁷ and A⁸; nostereoregularity; a glass-transition temperature of 0.4° C. in a rangebetween −100° C. and 250° C.; and a melting point of 133° C. Results areshown in Table 2.

Example 6

Example 3 was repeated except that the transition metal compound waschanged to 6.6 mg ofdichloro[2,6-bis{1-(2-methyl-6-isopropylphenylimino)ethyl}pyridine-κN]iron,thereby obtaining 82 mg of a homopolymer (white powder) of1,6-heptadiene having units represented by the formula (1).

The homopolymer was insoluble in chloroform or tetrahydrofuran at a roomtemperature, and was soluble in 1,1,2,2-tetrachloroethane at 130° C. Thehomopolymer had a number-average molecular weight (Mn) of 8,000; 90% ofa cis-form in view of its relative configuration between A⁷ and A⁸; and34% of erythrodiisotactic triad. Results are shown in Table 2.

Example 7

Example 3 was repeated except that (1) the transition metal compound waschanged to 6.0 mg ofdichloro[2,6-bis{1-(2,6-dimethylphenylimino)ethyl}pyridine-κN]iron, (2)an amount of the purified toluene was changed from 0.92 mL to 0.32 mL,and (3) 0.16 mL of 1,6-heptadiene was changed to 292 mg of4-(tert-butyldimethylsiloxy)-1,6-heptadiene (compound represented by theformula (3)), thereby obtaining 287 mg of a homopolymer (white powder)of 4-(tert-butyldimethylsiloxy)-1,6-heptadiene having units representedby the formula (1).

The homopolymer was insoluble in chloroform at a room temperature, andwas soluble in 1,1,2,2-tetrachloroethane at 130° C. The homopolymer hada cis-form in an amount of 100% in view of its relative configurationbetween A⁷ and A⁸, and had no stereoregularity. Results are shown inTable 2.

Example 8

Example 3 was repeated except that (1) the transition metal compound waschanged to 6.0 mg ofdichloro[2,6-bis{1-(2,6-dimethylphenylimino)ethyl}pyridine-κN]iron, and(2) 0.16 mL of 1,6-heptadiene was changed to 322 mg of4-triisopropylsiloxy-1,6-heptadiene (compound represented by the formula(3)), thereby obtaining 322 mg (quantitatively) of a homopolymer, of4-triisopropylsiloxy-1,6-heptadiene having units represented by theformula (1).

The homopolymer was insoluble in chloroform or tetrahydrofuran at a roomtemperature, and was soluble in 1,1,2,2-tetrachloroethane at 130° C. Thehomopolymer had a cis-form in an amount of 100% in view of its relativeconfiguration between A⁷ and A⁸, and had no stereoregularity. Resultsare shown in Table 2.

TABLE 1 Example 1 2 Polymerization condition Kind of monomer1,6-Heptadiene TIP-Hex (Note 1) Result Solubility Tetrahydrofuran hardlysoluble insoluble Chloroform soluble insoluble Tetrachloroethane —soluble Mn 10,000 — Trans-form (%) 100 100 Stereoregularity no no Tg (°C.) 3.2 — (Note 1): “TIP-Hex” means4-(triisopropylsiloxy)-1,6-heptadiene.

TABLE 2 Example 3 4 5 6 7 8 Polymerization condition Transition metalcompound (Note 2) Fe cpx-1 Fe cpx-2 Fe cpx-3 Fe cpx-4 Fe cpx-2 Fe cpx-2Kind of monomer (Note 3) Hex Hex Hex Hex Hex TIP-Hex Result SolubilityTetrahydrofuran insoluble insoluble insoluble insoluble — insolubleChloroform insoluble insoluble insoluble insoluble insoluble insolubleTetrachloroethane soluble soluble soluble soluble soluble Mn 3,000 6,00014,000 8,000 — — Configuration Trans-form (%) — — — — — Cis-form (%) 7095 95 90 100 100 Stereoregularity no no no no Erythrodiisotactic triad(%) 37 — — 34 — Tg (° C.) — — 0.4 — — — Melting point (° C.) — — 133 — —— (Note 2): “Fe cpx-1” means dichloro[2,6-bis{1-(2,6-diisopropylphenylimino)ethyl}pyridine - κN]iron. “Fe cpx-2” meansdichloro[2,6-bis{1-(2,6-dimethyl phenylimino)ethyl}pyridine - κN]iron.“Fe cpx-3” means dichloro[2,6-bis{1-(2,6-dichlorophenylimino)ethyl}pyridine - κN]iron. “Fe cpx-4” meansdichloro[2,6-bis{1-(2-methyl-6-isopropyl phenylimino)ethyl}pyridine -κN]iron. (Note 3): “Hex” means 1,6-heptadiene. “TIP-Hex” means4-(triisopropylsiloxy)-1,6-heptadiene.

1. A polymer containing units represented by the following formula (1):

wherein A¹, A², A³, A⁴, A⁵, A⁶, A⁷, A⁸, A⁹, A¹⁰, A¹¹, and A¹² areindependently of one another a hydrogen atom, a halogen atom, a hydroxylgroup, a nitrile group, an alkyl group, an aralkyl group, a silyl group,a siloxy group, an amino group, an amide group, an imide group, or ahydrocarbylthio group, and A³ and A⁴, A⁵ and A⁶, or A¹¹ and A¹² may belinked with each other to form a ring; m is 0 or 1; and n is an integerof 1 to 20, and wherein the units represented by the formula (1) containunits represented by the following fromula (2), whose relativeconfiguration between A⁷ and A⁸ is a trans-form:

wherein all the symbols contained in the formula (2) are the same asthose defined in the formula (1).
 2. The polymer according to claim 1,wherein the polymer is a polymer having more than 25% by mol ofthreodiisotactic triad, the total amount of the unit represented by theformula (1) being 100% by mol.
 3. The polymer according to claim 1,wherein the polymer is a polymer having more than 25% oferythrodiisotactic triad, the total amount of the unit represented bythe formula (1) being 100% by mol.
 4. The polymer according to claim 1,wherein the polymer Is a polymer having more than 25% of athreodisyndiotactic triad, the total amount of the unit represented bythe formula (1) being 100% by mol.
 5. The polymer according to claim 1,wherein the polymer is a polymer having more than 25% of anerythrodisyndiotactic triad, the total amount of the unit represented bythe formula (1) being 100% by mol.
 6. A process for producing a polymerhaving a repeating unit represented by the following formula (1),

wherein the units represented by the formula (1) contain unitsrepresented by the following formula (2), whose relative configurationbetween A⁷ and A⁸ is a trans-form:

which comprises the step of polymerizing a compound represented by thefollowing formula (3):

wherein A¹, A², A³, A⁴, A⁵, A⁶, A⁷, A⁸, A⁹, A¹⁰, A¹¹, and A¹² areindependently of one another a hydrogen atom, a halogen atom, a hydroxylgroup, a nitrile group, an alkyl group, an aralkyl group, a silyl group,a siloxy group, an amino group, an amide group, an imide group, or ahydrocarbylthio group, and A³ and A⁴, A⁵ and A⁶, or A¹¹ and A¹² may belinked with each other to form a ring; Z is a group of—(CH₂)_(n-1)—(CA⁹A¹⁰)_(m)H; two wavy lines displayed in the upper rightof the formula (3) mean variety in their configuration; and m is 0 or 1;n is an integer of 1 to
 20. 7. The process for producing a polymeraccording to claim 6, wherein the polymerization is carried out in thepresence of a polymerization catalyst formed by contacting a transitionmetal compound with an organoaluminum compound and/or boron compound. 8.The process for producing a polymer according to claim 7, wherein thetransition metal compound is a compound represented by the followingformula [I]:

wherein M² is a transition metal atom of Group 10 of the Periodic Tableof the elements; R³ and R⁴ are independently of each other a hydrogenatom, a halogen atom, an alkyl group, an aralkyl group, an aryl group, asilyl group, a siloxy group, an alkoxy group, an aralkyloxy group or anaryloxy group; R⁵ and R⁶ are independently of each other a hydrocarbylgroup having 1 to 30 carbon atoms; and R⁷ and R⁸ are independently ofeach other a hydrogen atom or a hydrocarbyl group having 1 to 20 carbonatoms, and R⁷ and R⁸ may be linked with each other to form a ring. 9.The process for producing a polymer according to claim 7, wherein thetransition metal compound is a compound represented by the followingformula [II]:

wherein M², R³, R⁴, R⁷ and R⁸ are the same as those defined in theformula [I]; R⁹ and R¹⁰ are independently of each other a hydrogen atom,a halogen atom, an alkyl group, an aralkyl group, a silyl group, asiloxy group, an alkoxy group, an aralkyloxy group, an amino group, anamide group, an imide group, or a hydrocarbylthio group; R¹¹ and R¹² areindependently of each other an aryl group having 7 to 20; and R¹³ andR¹⁴ are independently of each other a hydrogen atom, a halogen atom, analkyl group, an aralkyl group, an aryl group, a silyl group, a siloxygroup, an alkoxy group, an aralkyloxy group, an aryloxy group, an aminogroup, an amide group, an imide group, or a hydrocarbylthio group. 10.The process for producing a polymer according to claim 7, wherein thetransition metal compound is a compound represented by the followingformula [III]:

wherein M², R³, R⁴, R⁷ and R⁸ are the same as those defined in theformula [I]; R¹⁵, R¹⁶, R¹⁷ and R¹⁸ are independently of one another ahydrogen atom, a halogen atom, an alkyl group, an aralkyl group, an arylgroup having 6 carbon atoms, a silyl group, a siloxy group, an alkoxygroup, an aralkyloxy group, an aryloxy group, an amino group, an amidegroup, an imide group, or a hydrocarbylthio group; and R¹⁹ and R²⁰ areindependently of each other a hydrogen atom, a halogen atom, an alkylgroup, an aralkyl group, an aryl group, a silyl group, a siloxy group,an alkoxy group, an aralkyloxy group, an aryloxy group, an amino group,an amide group, an imide group, or a hydrocarbylthio group.
 11. Theprocess for producing a polymer according to claim 7, wherein thetransition metal compound is a compound represented by the followingformula [IV]:

wherein M³ is a transition metal atom of Group 8 to 11 of the PeriodicTable of the elements; R³ and R⁴ are the same as those defined in theformula [I]; and R²¹ to R²⁷ are independently of one another a hydrogenatom, a halogen atom, an alkyl group, an aralkyl group, an aryl group, asilyl group, a siloxy group, an alkoxy group, an aralkyloxy group, anaryloxy group, an amino group, an amide group, an imide group, or ahydrocarbylthio group, and any two or more of R²¹ to R²⁷ may be linkedwith one another to form a ring.